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Chapter 5 Chemical Quantities and Reactions

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1 Chapter 5 Chemical Quantities and Reactions
5.7 Mass Calculations for Reactions

2 Mass Calculations in Equations

3 Moles to Grams Suppose we want to determine the mass (g) of NH3 that
can be produced from 32 grams of N2. N2(g) + 3H2(g) NH3(g) Step 1 Use molar mass to convert grams of given to moles. 1 mole of N2 = g of N2 1 mole N and g N2 28.0 g N mole N2 32 g N2 x 1 mole N2 = mole of N2 28.0 g N2

4 Moles to Grams Step 2 Write a mole–mole factor from the coefficients in the equation. 1 mole of N2 = 2 moles of NH3 1 mole N and 2 moles NH3 2 moles NH mole N2

5 Moles to Grams Step 3 Convert moles of given to moles of needed using the mole–mole factor. 1.1 mole N2 x 2 moles NH3 = 2.2 moles of NH3 1 mole N2

6 Moles to Grams Step 4 Convert moles of needed substance to grams using molar mass. 1 mole of NH3 = g of NH3 1 mole NH3 and g NH3 17.0 g NH mole NH3 2.2 moles NH3 x g NH3 = 37 g of NH3 1 mole NH3

7 Learning Check How many grams of O2 are needed to produce 45.8 grams of Fe2O3 in the following reaction? 4Fe(s) + 3O2(g) Fe2O3(s) A g of O2 B g of O2 C g of O2

8 Solution How many grams of O2 are needed to produce 45.8 grams of
Fe2O3 in the following reaction? 4Fe(s) + 3O2(g) Fe2O3(s) Step 1 Use molar mass to convert grams of given to moles. 1 mole of Fe2O3 = g of Fe2O3 1 mole Fe2O and g Fe2O3 159.7 g Fe2O mole Fe2O3 45.8 g Fe2O3 x 1 mole Fe2O3 = mole of Fe2O3 159.7 g Fe2O3

9 Solution Step 2 Write a mole–mole factor from the coefficients in the equation. 3 moles of O2 = 2 moles of Fe2O3 3 moles O and moles Fe2O3 2 moles Fe2O moles O2 Step 3 Convert moles of given to moles of needed using the mole–mole factor. 0.287 mole Fe2O3 x 3 moles O = mole of O2 2 moles Fe2O3

10 Solution Step 4 Convert moles of needed substance to grams using molar mass. 1 mole of O2 = g of O2 1 mole O2 and g O2 32.0 gO mole O2 0.430 mole O2 x g O2 = g of O2 1 mole O2 The answer is B, 13.8 g of O2.

11 Learning Check The reaction between H2 and O2 produces 13.1 g of water. How many grams of O2 reacted? 2H2(g) O2(g) H2O(g) ? g g

12 Solution 2H2(g) + O2(g) 2H2O(g) ? g 13.1 g
Step 1 Use molar mass to convert grams of given to moles. 1 mole of H2O = g of H2O 1 mole H2O and g H2O 18.0 g H2O mole H2O 13.1 g H2O x 1 mole H2O = mole of H2O 18.0 g H2O

13 Solution Step 2 Write a mole–mole factor from the coefficients in the equation. 2 moles of H2O = 1 mole of O2 2 moles H2O and mole O2_ 1 moles O moles H2O Step 3 Convert moles of given to moles of needed using the mole–mole factor. 0.728 mole H2O x 1 mole O2 = mole of O2 2 moles H2O

14 Solution Step 4 Convert moles of needed substance to grams using molar mass. 1 mole of O2 = g of O2 0.364 mole O2 x g O2 = g of O2 1 mole O2


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