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power of hydrogen
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pH scale logarithmic scale If pH changes by factor of 1,
expressing H+1 concentration, [H+1] If pH changes by factor of 1, [H+1] changes by factor of 10 pH = -log[H+1]
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Molarity to pH To determine pH: express [H+1] in scientific notation
remember, [ ] means concentration of whatever is inside brackets log is the power of 10
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Molarity to pH for Pure water
tiny bit of ionization in pure water: H2O H+1 + OH-1 [H+1] = [OH-1] = 1 X 10-7 M pH = -log[H+1] = -(-7) = 7
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pH 3 2 1 pH .001 M or 1 X M 0.01 M 1 X M 0.1 M 1 X M 1 M 1X100 M [H+1]
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pOH =
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pH range 0 to (7 is neutral) pH = 0, strongly acidic pH = 14, strongly basic
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ACID or BASE? acids: [H+1] [OH-1] bases: [OH-1] [H+1]
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Relationships of: pH, pOH, [H+1] and [OH-1]
product of [H+1] and [OH-1] is always 1x10-1M add exponents when multiple in scientific notation sum of pH and pOH is always 14
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pH + pOH = 14 pH = 3, pOH = 11 pH = 7, pOH = pH = 10, pOH = 7
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if pH = 4 [H+1] = ? pOH = ? [OH-1] = ? 1 x 10-4 M 10 1x10-10 M
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if the [OH-1] = 1 X 10-3 pOH = ? pH = ? [H+1] = ? 3 14 – 3 = 11
1x10-11 M
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if the [H+1] = 1 x 10-5M pH = ? pOH = ? [OH-] = ? 5 14 – 5 = 9 1x10-9M
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6 1x10-2 1x10-5 3 Acidic or Basic pOH [OH-] (M) pH [H+] 1x10-3 1x10-11 11 A 9 B 1x10-9 5 A 2 1x10-12 12 1x10-8 8 1x10-6 B
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How to safely test pH use instruments – pH meter
use indicators – litmus paper or liquid indicators see if substance reacts with a metal other than Cu, Ag, or Au NEVER “taste”
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pH meters
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Indicator (l) substance that changes color over narrow pH range
use several indicators to narrow down pH range of substance See Table M
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