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Fig. 5 Scheme of photobleaching mechanism.
Scheme of photobleaching mechanism. (A) Schematic representation of a strongly coupled system and transitions between various states. (B) SF as a function of Rabi splitting. Circles represent experimental results and are normalized by the bleaching rate of uncoupled J-aggregates. The solid blue line represents the theoretical dependence of the SF on the Rabi splitting. (C) Schematic representation of the photobleaching process as a function of plasmon-exciton detuning. The visibility/transparency of arrows represents high/low probability of the corresponding transition, demonstrating that highly red-detuned particles are much more stable than highly blue-detuned ones. (D) SF as a function of plasmon resonance frequency. Circles represent experimental results and are normalized by the bleaching rate of uncoupled J-aggregates. The solid blue line represents the relative SF (normalized by the SF at zero detuning) calculated using Eq. 4 at ΩR = 200 meV. Note the logarithmic scale and different vertical axes for the experimental and theoretical data. Battulga Munkhbat et al. Sci Adv 2018;4:eaas9552 Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).
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