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Published bySteffen Edvin Ødegaard Modified over 5 years ago
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Theory Reveals Novel Chemistry of Photonic Molecules
Matthew Du Chem Volume 5, Issue 5, Pages (May 2019) DOI: /j.chempr Copyright © Terms and Conditions
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Figure 1 Remote Control of Chemistry with Optical Cavities
(A) Simplified visualization. Top: a “pump” pulse excites a polariton whose character is predominantly remote catalyst (RC) and its cavity. Bottom: as a result, a subsequent “probe” pulse efficiently excites a polariton whose character is predominantly reactant and its cavity, and the product is formed. (B) Energetic representation. Left: after pump excitation, the highest polariton relaxes to RC dark states. Right: as a result of the excited RC population just formed, the lowest polariton becomes resonant with the probe pulse and gains reactant character; efficient transfer into the product-yielding state occurs. Adapted from Du et al.2 Chem 2019 5, DOI: ( /j.chempr ) Copyright © Terms and Conditions
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Chem 2019 5, DOI: ( /j.chempr ) Copyright © Terms and Conditions
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