1. Organic Chem Quizzer Basic Skills

2. 1. Name the functional group. a)-OH b)-NH 2 c)C=O d)COOH e)C=C

3. 2. Name the organic family. a)R-O-R’ b)R-CO-R’ c)ROH d)RCONHR’ e)RHO f)RX g)RNHR’

4. 3. Predict the products. a)RCOOH + R’OH  b)alkene + X 2  c)RX + benzene  d)CO + 2 H 2  e)ROH + O 2  f)alkyne + 2 X 2  g)RCOOR’ + NaOH 

5. h) alkane + X 2  i) RX + NH 3  j) ROH  k) RCOOH + RNHR’  l) 2 0 ROH + (O)  m) RHO + (O)  n) alkene + H 2 O  o) alkyne + 2 H 2 

6. p) 1 0 ROH + (O)  q) benzene + X 2  r) benzene + HNO 3  s) alkene + HX  t) 3 0 ROH + (O)  u) RCOR’ + (O)  v)RX + H 2 NR’  w) ROH + R’OH 

7. Answers: 1. Functional Groups a)hydroxyl group b)amino group c)carbonyl group d)carboxyl group e)double bond

8. 2. Organic Families a)ether b)ketone c)alcohol d)amide e)aldehyde f)alkyl halide g)amine (2 0 )

9. 3. Predicting Products a)RCOOR’ + H 2 O, Esterification b)RX, Addition (halogenation) c)benzene-R + HX, Sub (alkylation) d)CH 3 OH, Reduction of CO (g) e)CO 2 + H 2 O, Combustion f)RX, Addition (halogenation) g)RCOO - Na + + R’OH, Hydrolysis

10. h)RX + HX, Sub (halogenation) i)RNH 2 + HX, Sub (prep. of amine) j)alkene + H 2 O, Dehydration of ROH k)RCONRR’ + H 2 O, Condensation (to form amide) l)RCOR’ + H 2 O, Oxidation m)RCOOH, Oxidation n)ROH, Addition (hydration) o)alkane, Addition (hydrogenation)

11. p)RHO + H 2 O, Oxidation q)benzene-X + HX, Sub (halogenation) r)benzene-NO 2 + H 2 O, Sub (nitration) s)RX, Addition (hydrohalogenation) t) NR (no reaction), 3 0 ROH do not oxidize u)NR (no reaction), ketones do not oxidize v)RNHR’ + HX, Sub (to form an amine) w) R-O-R’ + H 2 O, Condensation