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The Structure of an Atom
Chapter 3
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Modern Atomic Theory
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Early Theories Greek Philosophers Democritus 4 Elements Aristotle
Earth Fire Wind Water Democritus Atoms make up matter Aristotle Refuted Democritus and atom’s existence forgotten
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Deomcritus Atoms Differences in atoms Modern Atomic Theory
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Dalton’s Atomic Theory
All matter is composed of extremely small particles called atoms. All atoms of a given element are identical. Atoms cannot be created, divided into smaller particles, or destroyed. Different atoms combine in simple whole number ratios to form compounds. In a chemical reaction, atoms are separated, combined or rearranged.
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Dalton’s Atomic Theory
All matter is composed of extremely small particles called atoms. All atoms of a given element are identical. Atoms cannot be created, divided into smaller particles, or destroyed. (This part proven wrong) Different atoms combine in simple whole number ratios to form compounds. In a chemical reaction, atoms are separated, combined or rearranged. What exactly do notes help with?
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Modern Atomic Theory Democritus Atoms Differences in atoms Dalton
Sameness Created/destroyed Combination Rearrangement
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The Atom The smallest particle of an element that retains the properties of the element Has three main parts that have not been discovered at this point.
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Subatomic Particles and the Atom
Cathode ray tube Stream of charged particles (electrons). Robert Millikan Oil drop experiment Found the charge/mass ratio for an electron J. J. Thompson Used cathode ray tube to prove existence of electron. Then used a charge to mass ratio to find the mass, proving part of Dalton’s theory wrong Proposed “Plum Pudding Model”
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Atoms composed of electrons
Democritus Atoms Differences in atoms Thompson Atoms composed of electrons Modern Atomic Theory Dalton Atoms Sameness Created/destroyed Combination Rearrangement
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Ernest Rutherford Gold Foil experiment
Used to prove the existence of a positively charged core (Nucleus) The results were “like firing a large artillery shell at a sheet of paper and having the shell come back and hit you!”
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Modern Atomic Theory Democritus Atoms Thompson
Differences in atoms Thompson Atoms composed of electrons Modern Atomic Theory Rutherford Positively Charged Nucleus Dalton Atoms Sameness Created/destroyed Combination Rearragement
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Subatomic Particles and the Atom
Chadwick Worked with Rutherford. Noted there was energy in the nucleus, but wasn’t the protons. Concluded that neutral particles must also exist in nucleus. Mosley Assigned atomic number to atoms Bohr Designed “Bohr Model” of the atom.
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Modern Atomic Theory Deomcritus Atoms Thompson
Differences in atoms Thompson Atoms composed of electrons Modern Atomic Theory Rutherford Positively Charged Nucleus Dalton Atoms Sameness Created/destroyed Combination Rearragement Chadwick Neutrons exist in Nucleus
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Subatomic Particles and the Atom
Three main particles: (see chart in Ch. 3) Proton Positive In nucleus Neutrons Neutral Electrons Negative Orbiting the nucleus (not inside)
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Atomic Differences Atomic Number Isotopes Atomic Mass Unit
Distinguishes one atom from another. = #p+ (& #e- for a neutral atom) Isotopes Differ in mass number Mass # = #p+ + #no Change is in # no Atomic Mass Unit Defined as 1/12 mass of a Carbon-12 atom p+ = 1 amu no = 1 amu e- = 0 amu
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Atomic Differences Mass on the periodic table is based on the percent abundance of each isotope of that element. Therefore it is a decimal. Ex: Chlorine exist naturally as Cl-37 and Cl-35. Cl-37 is about 75% and Cl-35 is about 25%. So, (37 X .75) + (35 X .25) = 36.5 amu. See Ex problem on pg 103 for more ideas.
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Questions? Ask now, or forever come in the morning for them!
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