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Oxidation of alcohols
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They will not react unless acid is present.
Acidified potassium permanganate (H+/KMnO4), and acidified potassium dichromate (H+/K2Cr2O7) are important oxidising agents. They will not react unless acid is present. Purple H+/MnO4- turns colourless when it has reacted. Orange H+/Cr2O72- turns blue/green when it has reacted.
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Primary alcohol with acidified dichromate; secondary alcohol with acidified permanganate, tertiary alcohol with acidified dichromate. The reactions are very slow unless heated in a water bath.
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The primary alcohol has turned the dichromate blue/green.
The secondary alcohol has decolourised the permanganate. The tertiary alcohol has not reacted with the dichromate.
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Primary alcohols are oxidised by acidified dichromate or acidified permanganate. They form an aldehyde, and then a carboxylic acid. Secondary alcohols are also oxidised by these oxidising agents. They form ketones. Tertiary alcohols do not react with oxidising agents such as permanganate and dichromate.
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