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Published byWyatt Tyre Modified over 9 years ago
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Lipids Triglycerides- fats and oils Phospoglycerides- lecithin
Sterols- cholesterol
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Triglycerides Neutral fats- triesters of fatty acids and glycerol Fats- solid at room temperature Olis- liquid at room temperature
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Fatty acids Stearic acid Linoleic acid Glycerol
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Trigycerides + H2O Glycerol + 3 fatty acids Triglyceride + water
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Saturated or unsaturated fats/oils?
Saturated- no double bonds Unsaturated- one or more double bonds Polyunsaturated- many double bonds Cis- or trans-double bonds Lauric acid Oleic acid
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Stearic acid, Mp 70 ºC Linoleic acid, -6, Mp -5 ºC -6 and -3 fatty acids are essential
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Linoleic acid, -6, Mp -5 ºC Linolenic acid, -3, Mp -11 ºC -6 and -3 fatty acids are essential
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Phosphoglycerides
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Cell membrane
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Steroids Cholesterol, sexual hormones
Carotenoids – fat-soluble vitamins
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Stereoids Oestradiol Cholesterol Testosterone
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Lipid transport in the cells
Low-density lipoproteins LDL- good High-density lipoproteins HDL- bad
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Carotenoids Me = CH3 Vitamin A (retinol) red
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Carotenoides, forts Vitamin D Vitamin E Vitamin K
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Analysis of lipids Iodine or bromine number Addition of I2 or Br2
Unsaturated fatty acid Brominated fatty acid
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Roles of lipids in the body (+)
Energy storage Insulation and protection of organs Structural components of cell membranes -3 poly-unsaturated fatty acids reduce the risk of heart disease poly-unsaturated fats may lower levels of LDL cholesterol
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Roles of lipids in the body (-)
Increased risk of heart disease from elevated levels of LDL cholesterol and trans-fatty acids The major source of LDL cholesterol is saturated fats (C12, C14 and C16 fatty acids) Obesity
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