1. The geochemical atlas of agricultural and grazing land soil of Italy based on GEMAS samples Benedetto De Vivo, Domenico Cicchella, Stefano Albanese, Enrico Dinelli, Lucia Giaccio, Annamaria Lima, Paolo Valera Professor of Environmental Geochemistry Università degli Studi di Napoli Federico II, Adjunct Professor of Volcanology and Exploration Geochemistry Virginia Polytechnic Institute & State University, Blacksburg, VA, USA Presented by Benedetto De Vivo FAO Headquarters - Rome, 5/12/2013 EuroGeoSurveys WORKSHOP

2. The FOREGS experience in Europe as a starting point http://weppi.gtk.fi/publ/foregsatlas/ (From Salminen et al., 2005, Fig. 1, p.359) (From Salminen et al., 2005, Fig. 1, p.357)

3. The FOREGS database for Italy – Publication of an Atlas

4. Legend Sample locations (FOREGS) Integrated sample locations for Geochemical Atlas of Italy FOREGS sampling in Italy 349 geochemical maps for 70 elements/parameters in 6 environmental media: - Humus - Topsoil - Subsoil - Floodplain sediment - Stream sediment - Stream water The FOREGS database for Italy 58 sampling locations (From De Vivo et al., 2009, Fig. 3.2, p.36)

5. The FOREGS database for Italy | Geochemical Mapping (From De Vivo et al., 2009, p.384)(From De Vivo et al., 2009, p.479) (From De Vivo et al., 2009, p.387) (From De Vivo et al., 2009, p.446) (From De Vivo et al., 2009, p.468)

6. The GEMAS database for Italy 121 samples of agricultural soil (0-20 cm) and 121 samples of grazing land soil (0-10 cm) were collected in Italy at an average sample density of 1 site/2500 km 2

7. Grazing land soil The GEMAS database for Italy Agricultural soil

8. The geological settings of Italy

9. Grazing land soil Agricultural soil The GEMAS database for Italy | pH (Soil acidity)

10. The GEMAS database for Italy | Arsenic Agricultural soil Aqua Regia / ICP-MS versus Aqua Regia / ICP-MS versus XRF

11. The GEMAS database for Italy | Arsenic Grazing land soil Aqua Regia / ICP-MS versus Aqua Regia / ICP-MS versus XRF

12. The GEMAS database for Italy | Arsenic Agricultural soil MMI® / ICP-MS (From Reimann et al., 2014, Fig. 11.9.1, p.148)

13. The GEMAS database for Italy | Beryllium Agricultural soil Grazing land soil Aqua Regia / ICP-MS

14. The GEMAS database for Italy | Chromium Agricultural soil Aqua Regia / ICP-MS versus MMI® / ICP-MS Aqua Regia / ICP-MS versus MMI® / ICP-MS

15. The GEMAS database for Italy | Lead Agricultural soil Aqua Regia / ICP-MS versus XRF Aqua Regia / ICP-MS versus XRF

16. The GEMAS database for Italy | Lead Grazing land soil Aqua Regia / ICP-MS versus XRF Aqua Regia / ICP-MS versus XRF

17. The GEMAS database for Italy | Lead Agricultural soil MMI® / ICP-MS (From Reimann et al., 2014, Fig. 11.41.1, p.336)

18. The GEMAS database for Italy | Thallium Agricultural soil Aqua Regia / ICP-MS versus MMI® / ICP-MS Aqua Regia / ICP-MS versus MMI® / ICP-MS

19. Agricultural soil Aqua Regia / ICP-MS MMI® / ICP-MS XRF MMI® / ICP-MS XRF

20. Thank you The geochemical atlas of agricultural and grazing land soil of Italy based on GEMAS samples Benedetto De Vivo, Domenico Cicchella, Stefano Albanese, Enrico Dinelli, Lucia Giaccio, Annamaria Lima, Paolo Valera References

21. REFERENCES SLIDE 2: Salminen, R. (Chief-editor), Batista, M.J., Bidovec, M., Demetriades, A., De Vivo, B., De Vos, W., Duris, M., Gilucis, A., Gregorauskiene, V., Halamic, J., Heitzmann, P., Lima, A., Jordan, G., Klaver, G., Klein, P., Lis, J., Locutura, J., Marsina, K., Mazreku, A., O’Connor, P.J., Olsson S.Å., Ottesen, R.T., Petersell, V., Plant, J.A., Reeder, S., Salpeteur, I., Sandström, H., Siewers, U., Steenfelt, A. & Tarvainen, T. (Editors), 2005. FOREGS Geochemical Atlas of Europe, Part 1: Background Information, Methodology and Maps. Geological Survey of Finland, Espoo, 526 pp., 36 figures, 362 maps, http://weppi.gtk.fi/publ/foregsatlas/. http://weppi.gtk.fi/publ/foregsatlas/ SLIDES 3, 4, 5: De Vivo, B., Lima, A., Cicchella, D., Frizzo, A.D., Raccagni, L., Bove, M.A., Albanese, S., Grezzi, G., Sabatini, G., Protano, G. & Riccobono, F., 2009. Atlante geochimico-ambientale d’Italia – Geochemical environmental atlas of Italy. Aracne editrice S.r.l., Rome, 516 pp. SLIDES 6-19: De Vivo, B., Cicchella, D., Albanese, S., Dinelli, E., Giaccio, L., Lima, A., Valera, P., 2014. The geochemical atlas of agricultural and grazing land soil of Italy based on GEMAS samples. Aracne Editrice, Roma (in press). SLIDE 12 CP plot: Reimann, C., Demetriades, A., Birke, M., Filzmoser P., O’Connor, P., Halamic, J., Ladenberger, A. & the GEMAS Project Team, 2014. Distribution of elements/parameters in agricultural and grazing land soil of Europe. Chapter 11 In: C. Reimann, M. Birke, A. Demetriades, P. Filzmoser & P. O’Connor (Editors), Chemistry of Europe's agricultural soils – Part A : Methodology and interpretation of the GEMAS data set. Geologisches Jahrbuch (Reihe B), Schweizerbarth, 101-472.