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Electronegativity and Bond Type
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General Bonds are formed when two atoms share or transfer electrons.
As the atoms move closer together, the electrons from each atom are attracted to the protons of another atom.
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Bonds Two main types: covalent bonds and ionic bonds
Covalent bonds- electrons are shared equally or somewhat shared. Ionic bonds- electrons are completely transferred from one atom to another. This is what causes cations and anions in ionic compounds
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Electronegativity How do you determine what bond is formed between two atoms? Look at the electronegativity values of the atoms. Electronegativity-the ability of an atom to attract electrons in a chemical bond.
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Electronegativity Atoms with higher electronegativity attract electrons more strongly. If atoms form a bond, the electrons are held close. If the electronegativity difference is large enough, electrons can be pulled away from the other atom.
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Electronegativity Each atom has an electronegativity value.
Elements that have low values lose electrons easily. Elements that have high values gain electrons easily.
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Bond Types Little or no difference in electronegativity allows for a covalent bond. Ex: H2, both atoms have an electronegativity of 2.1 = 0 (no difference in electronegativity)
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Bond Type When the electronegativity difference is large, electrons are not shared equally. The bond is ionic.
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Bond Types Nonpolar covalent bonds = 0.0-0.39
Ionic bonds = 1.7 or higher
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Predicting Bond Types To predict the bond type for two atoms, find the electronegativity value for each element Subtract the smaller value from the larger.
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Examples Predict the bond type in: HCl NaCl CCl4 NH3
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