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FUEL CELLS Mikael Paronen FD, Avdelningschef Företagsekonomi. Medie och teknik ARCADA
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SIDA2 Fuel Basics Electrochemical conversion No thermal limitations; Carnot cycle No burning; electrochemical reaction H 2 + ½ O 2 => H 2 O // 1.2 V Losses: kinetics and resistivity ====> U: 0.15 -1.0 V
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SIDA3 Fuel cells; structure http://www.hydrogencommerce.com/FCHandbook/TechOver1-1FCDesc.htm
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SIDA4 Fuel cell: operational principle http://www.corrosion-doctors.org/Batteries/e-icurve.htm
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SIDA5 Fuel Cell Future Free from hazardous emissions Low green house emissions Solar energy supported Energy efficiency Energy density Cost effective Mobile
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SIDA6 Why now??? Invented 1839 Applied by NASA 1960s Need for new materials Lack of cheap energy
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SIDA7 Selection and types of fuel cells High power = high temperature Fuel cells classified by electrolyte Polymer electrolyte: max 100 C Alkaline90-100 C Phosphoric acid150-200 C Molten carbonate600-700 C Solid oxide650-1000 C
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SIDA8 Portable cells Based on polymers as electrolytes Fuel alternatives: Hydrogen Methanol Formic Acid NaBH 4
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SIDA9 Solar cells vs. fuel cells Solar Cells: “From light to Electricity” Power output 300 W/m 2 Dependent on light Fuel Cells: From Fuel to Electricity Power density max 10 kW/m 2 Dependent of fuelling Connection between solar cells and fuel cells: reversible cells// electrolysis cells (light =>electricity => electrolysis of water => hydrogen gas => storage => electricity)
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SIDA10 Fuel Cell project at Arcada Focused on small devices (0.1-20 W) Scope in component integration Separate projects in the development of Electrode/catalyst layer DC/DC Converters Composite Materials (electron conductive) Management of Fuel and Waste at the Anode side
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SIDA11 Lab excursion Walter Virta (elektroteknik): fuel cell basics and testing Maia Mangdalezha: Thermodynamic and mathematical optimization of the anode side Mikael Paronen: materials development needed
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SIDA12
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