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11 Wastewater Treatment 11.1 Boundary conditions
Technische Universität Dresden Peter Krebs Department of Hydro Science, Institute for Urban Water Management Urban Water Systems 11 Wastewater Treatment 11.1 Boundary conditions 11.2 Layout of a wastewater treatment plant (WWTP) 11.3 Mechanical treatment 11.4 Biological treatment 11.5 Final clarification Urban Water Systems 11 Wastewater treatment
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11.1 Boundary conditions 11 Wastewater treatment Urban Water Systems
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Total capacity in mio PE
Wastewater treatment in Germany In 2000 more than 10‘000 communal WWTPs Class Number Total capacity in mio PE > 100’000 272 83.1 10’000 – 100’000 1’817 56.1 2’000 – 10’000 2’617 12.3 50 – 2’000 5’677 3.2 Urban Water Systems 11 Wastewater treatment
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Effluent standards COD (mg/l) BOD5 (mg/l) NH4-N (mg/l) N* (mg/l)
Ptot (mg/l) Class 1 < 1000 PE kg BOD5 / d 150 40 - - - 2 < 5000 PE kg BOD5 / d 110 25 - - - 3 < PE kg BOD5 / d 90 20 10 - - 4 < PE kg BOD5 / d 90 20 10 18 2 5 > PE kg BOD5 / d 75 15 10 13 1 * N = Sum of NH4+, NO3-, und NO2- Urban Water Systems 11 Wastewater treatment
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Load variation in WWTP inlet
10 20 30 40 50 60 70 00:00 04:00 08:00 12:00 16:00 20:00 Time (hh:mm) COD-load (kg/h) 1 2 3 4 5 6 7 NH -load (kg/h) Daily average COD and -load COD-load Urban Water Systems 11 Wastewater treatment
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Wet-weather load of NH4 and TSS from sewer
16 NH4 load 14 Flow rate ) C 3 TSS load 12 d Q 10 load / (Qd·C0) 2 8 TSS load / ( 6 4 ; NH 1 4 d Q / Q 2 10:00 12:00 14:00 16:00 18:00 20:00 22:00 0:00 2:00 Urban Water Systems 11 Wastewater treatment
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WWTP load with NH4+ at storm event
Time Flow rate Time Conc., load Load Concentration Urban Water Systems 11 Wastewater treatment
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11.2 Layout of a wastewater treatment plant (WWTP)
Urban Water Systems 11 Wastewater treatment
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precipitation chemical
Layout of a WWTP Mechanical treatment Biological treatment precipitation chemical Screen Grid chamber Fat chamber Primary clarifier Activated sludge tank Secondary clarifier River, filtration Sand Fat Primary sludge Return sludge Thickening Secondary sludge Excess sludge Biogas Use, dewatering, drying, incineration, Disposal disposal, incineration Wash, disposal Digestion Storage Urban Water Systems 11 Wastewater treatment
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Example: WWTP Chemnitz-Heinersdorf
Urban Water Systems 11 Wastewater treatment
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Wastewater HRT (h) Sludge SRT (d)
Typical residence time in reactors Wastewater HRT (h) Sludge SRT (d) Mechanical pre-treatment 0.2 0.01 Primary clarifier 1.5 1 Activated sludge tank 10 10 Secondary clarifier 5 2 Sludge thickener 2 Digester 20 Storage 100 < 1 d > 100 d Urban Water Systems 11 Wastewater treatment
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11.3 Mechanical treatment 11 Wastewater treatment Urban Water Systems
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Automatically cleaned trash rack
Urban Water Systems 11 Wastewater treatment
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Sieve Slotted sieve ≥ 0.5 mm Perforated tin ≥ 3 mm
Hans Huber AG, Typ Ro9 Urban Water Systems 11 Wastewater treatment
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Basics for rack design Flow velocity: 0,6 v 2,5 m/s
Widen flume to compensate for racks cross section Consider backwater effect Hydraulics: + due to clogging lower bottom to compensate for backwater effect Safety for maintenance (redundant) Building around racks (Frost, smell) Urban Water Systems 11 Wastewater treatment
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Surface load: qA = Q / A (Hazen, 1904)
VS H Critical case Settling condition VS qA Independent of H ! Urban Water Systems 11 Wastewater treatment
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Grid chamber In connection with combined systems
Effects of non-organic particles: Abrasion of steel (e.g. pumps) Clogging (Sludge hopper, pipes, Pumps) Sedimentation (activated sludge tank, digester) High maintenance requirements Sludge in sand is hindering Sand in sludge is detrimental for operation ! Urban Water Systems 11 Wastewater treatment
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Empirical sedimentation velocities
Kalbskopf, 1966 Particle diameter Sedimentation velocity [mm] = 100% [cm/s] = 90% = 85% 0,125 0,160 0,200 0,250 0,315 0,17 0,29 0,46 0,74 1,23 0,26 0,44 0,78 1,25 2,00 0,31 0,56 0,99 1,60 2,35 Urban Water Systems 11 Wastewater treatment
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Design rules Flow velocity: 0,3 m/s Width extending with height
Length: Sand collector: appr. 0,2 x 0,3 m (not too large!) Venturi flow measurement after grid chamber Urban Water Systems 11 Wastewater treatment
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Aerated grid chamber Urban Water Systems 11 Wastewater treatment
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Efficiency of primary clarifier
100 90 settleable solids 80 70 TSS 60 50 Efficiency (%) 40 30 BOD 5 20 10 1 2 3 4 5 Residence time HRT (h) Urban Water Systems 11 Wastewater treatment
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Effects of primary clarifier on wastewater
Compound Unit Inlet Outlet* TSS g TSS / m3 360 180 0.5 BOD5 g O2 / m3 300 230 0.23 COD g O2 / m3 600 450 0.25 TKN g N / m3 60 56 0.067 NH4-N g N / m3 40 40 NO2-N g N / m3 NO3-N g N / m3 1 1 Ptot g P / m3 10 9 0.1 Alkalinity mol HCO3- / m3 = f(Drinking water) + NH4-N * Short residence time Urban Water Systems 11 Wastewater treatment
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Rectangular sedimentation tank
Primary / secondary clarifier Flight scraper Effluent weir Inlet Effluent to activated sludge tank or to receiving water Sludge withdrawal Surface: Primary clarifier qA = 2 to 6 m/h Secondary clarifier qA = 0.5 to 1.5 m/h Urban Water Systems 11 Wastewater treatment
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11.4 Biological treatment 11 Wastewater treatment Urban Water Systems
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Biological treatment Suspended biomass Activated sludge system
suspended through turbulence sludge flocs with 0.1 – 1 mm diameter degradation related to biomass Increase suspended biomass concentration Sessile biomass Biofilm system biofilm on carrier little erosion degradation related to biofilm surface area Increase of specific surface area Urban Water Systems 11 Wastewater treatment
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Important micro-biological processes
Growth Implementation of C, N, P in biomass Decay If external nutrients are rare Hydrolysis Heavily easily degradable substances, through encymes Aerobic degradation organic compounds CH2O + O2 CO2 + H2O Nitrification NH O2 NO3- + H2O + 2 H+ Denitrification 5 CH2O + 4 NO H+ 2 N2 + 5 CO2 + 7 H2O Urban Water Systems 11 Wastewater treatment
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Growth of bacteria Doubling time tD 0·tD 1·tD 2·tD 3·tD i·tD ... n·tD
20 21 22 23 2i ... 2n Activated sludge: tD = 6 h Sludge age = 10 d Urban Water Systems 11 Wastewater treatment
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Growth of bacteria Growth is limited through nutrients and oxygen
Substrate, nutrients, O 2 m (T -1 ) Growth max,2/2 max,1/2 Specific growth rate KS,1 KS,2 XB = Biomass concentration max = Maximum specific growth rate S = Substrate concentration KS = Half saturation constant Urban Water Systems 11 Wastewater treatment
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Activated sludge system
Activated sludge tank Secondary clarifier Air, O2 Sedimentation Effluent Inlet Nutrients Bacteria Return sludge Excess sludge Urban Water Systems 11 Wastewater treatment
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Sludge inventory in activated sludge system
Activated sludge tank Secondary clarifier XAST Q Q + QRAS Q XAST Xe QRAS = R·Q (QWAS) XRAS (XWAS) Sludge balance in equilibrium mit Urban Water Systems 11 Wastewater treatment
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Flow scheme of activated sludge system
Hydraulic wash-out of sludge to secondary clarifier sludge must be returned to activated sludge tank Activated sludge is circled 20 to 50 times sludge concentration in activated sludge tank is maintained Excess sludge is withdrawn from system equivalent to sludge production Through increased hydraulic loading (wet-weather condition) sludge is shifted to secondary clarifier Urban Water Systems 11 Wastewater treatment
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Dynamic sludge shift Sludge bed Activated sludge tank
500 1000 1500 2000 2500 3000 0,5 1 1,5 2 Time (d) Sludge mass (kg COD) Activated sludge tank 200 400 600 800 1000 1200 1400 0,5 1 1,5 2 Time (d) Sludge mass (kg COD) Sludge bed Urban Water Systems 11 Wastewater treatment
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Aeration in an actvated sludge tank
Oxygen Bacteria Organic compounds Sludge Effluent, water and sludge Air Inflow from mecha-nical treatment Return sludge Dimension: communal wastewater treatment 2 m3 wastewater per m3 reactor volume and day Urban Water Systems 11 Wastewater treatment
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Dimensioning on sludge loading
BOD5 inlet load is related to sludge mass in activated sludge tank (AST) F/M BOD5 loading related to dry sludge mass (Food/Microorganisms) Q Inflow to WWTP (m3/d) BOD5,in BOD5 concentration in inlet (kg BOD5 / m3) VAST Volume of activated sludge tank (m3) XAST Sludge concentration in activated sludge tank (kg TSS / m3) Urban Water Systems 11 Wastewater treatment
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Dimensioning on sludge age
Sludge production is related to sludge mass in activated sludge tank SRT Sludge age in (d), 3 – 15 d ESPBOD Specific excess sludge production per BOD5 converted (kg TSS / kg BOD5) SP Sludge production (kg TSS / d) Urban Water Systems 11 Wastewater treatment
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Nutrients demand of micro-organisms
Nitrogen iN = – (g N / g BOD5) Phosphorous iP = – (g P / g BOD5) Partial elimination of nutrients Wastewater composition in the inlet 300 (g BOD5/m3) 60 (g TKN/m3) 12 (g TP/m3) Effluent concentrations after 100% BOD5 degradation TKNeff = TKNin – iN·BOD5,in = 60 – 0.045·300 = (g N / m3) TPeff = TPin – iP·BOD5,in = 12 – 0.015·300 = (g P / m3) Enhanced nutrients removal is necessary! Urban Water Systems 11 Wastewater treatment
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Nitrification NH4+ NO3-
Nitrifying organisms („autotrophic biomass“ XA) have a low growth rate A With production of autotrophic biomass and a safety factor SF the necessary sludge age yields high sludge age necessary to omit nitrifiers from being washed out of the system Volume of activated sludge tank must be large Urban Water Systems 11 Wastewater treatment
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Development of activated sludge system
aerobic C-Elimination aerobic Nitrification anoxic aerobic De-nitrification anaerobic anoxic aerobic „Bio-P“ Urban Water Systems 11 Wastewater treatment
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Oxygen consumption Oxygen introduction Introduction Consumption
SOC Specific O2-consumption (kg O2 / kg BOD5) cs O2 saturation concentration (g O2 / m3) c O2 concentration (g O2 / m3) f Peak factor for variations (-) SOI Spec. O2 introduction rate to clean water (kg O2 / (m3·h)) Reduction factor for wastewater (0.4) 0.6 – 0.8 The smaller the actual oxygen concentration, the more efficient is the oxygen introduction Urban Water Systems 11 Wastewater treatment
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Specific oxygen consumption SOC (kg O2 / kg BOD5)
Sludge age in d (°C) 4 8 10 15 20 25 10 0.85 0.99 1.04 1.13 1.18 1.22 12 0.87 1.02 1.07 1.15 1.21 1.24 15 0.92 1.07 1.12 1.19 1.24 1.27 18 0.96 1.11 1.16 1.23 1.27 1.30 20 0.99 1.14 1.18 1.25 1.29 1.32 Peak factors for C und N degradation fC 1.30 1.25 1.20 1.20 1.15 1.10 fN < 20‘000 PE - - - 2.50 2.00 1.50 > 100‘000 PE - - 2.00 1.80 1.50 - Urban Water Systems 11 Wastewater treatment
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Design rules Type of biological reactor Without nitrification
Nitrification >10°C Denitrifi-cation Simultaneous aerobic sludge stabilisation SRT < 20‘000 PE 5 10 12 – 18 25 > 100‘000 PE 4 8 10 – 16 – F/M (kg BOD5 / (kg TS · d)) 0.30 0.15 0.12 0.05 ESPBOD (kg TS / kg BOD5) 0.9 – 1.2 0.8 – 1.1 0.7 – 1.0 1.0 Urban Water Systems 11 Wastewater treatment
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Concentrations in a plug flow areation tank
Qin QRS QES O2 BSB5 NH4+ NO32- Urban Water Systems 11 Wastewater treatment
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Primary clarification Secondary clarification
Trickling filter Biofilm grown on internal surface Trickling filter Primary clarification Secondary clarification Recirculation Return sludge Sludge withdrawal Urban Water Systems 11 Wastewater treatment
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Dimensioning of trickling filter
Surface loading BSu Surface loading (g BOD5 / (m2·d)) without nitrification 4 (g BOD5 / (m2·d)), with nitrifi. 2 (g BOD5 / (m2·d)) Q Inflow to trickling filter (m3/d) BOD5,in BOD5 inlet concentration (kg BOD5 / m3) VTF Volume of trickling filter (m3) a Specific biofilm surface per volume of trickling filter (m2 / m3 TF) 100 – 140 – 180 (m2 / m3 TF) Urban Water Systems 11 Wastewater treatment
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Degradation in trickling filter
Concentration BOD5 Trickling filter NH4+ N03- C-degradation and nitrification are separated in space Urban Water Systems 11 Wastewater treatment
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11.5 Final clarification 11 Wastewater treatment Urban Water Systems
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Functions of final clarifiers
Separation of sludge and cleaned wastewater through Sedimentation Clarification Low effluent concentration Storage of sludge shifted from actibated sludge tank, namely under wet-weather conditions Thickening High return sludge concentration Geometry Circular, flow from centre to periphery Rectangular, longitudinal flow Rectangular, lateral flow Vertical, upward flow Urban Water Systems 11 Wastewater treatment
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Particle-Interaction
Sedimentation Primary clarifier Final clarifier, separation zone low Free settling Flocculating settling Final clarifier, sludge bed Concentration Hindered settling Final clarifier, bottom Thickening high none flocculating Particle-Interaction Urban Water Systems 11 Wastewater treatment
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Sludge volume index SVI
SVI is an indicator for volume of sludge flocs and their settling characteristics 0.5 h H hS X0 V Sludge volume (ml/l) (ml / g TSS) Urban Water Systems 11 Wastewater treatment
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Final clarifier, idealised functions
Inlet zone Effective zone Clear water layer Separation layer > 3 m Storage layer Thickening layer ATV A131 (2000) Urban Water Systems 11 Wastewater treatment
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Dimensioning of surface
Surface overflow rate Sludge overflow rate Limit values qA qSV (m/h) (l/(m2·h) Horizontal flow tanks 1.6 500 Vertical flow tanks 2.0 650 ATV A131 (2000) Urban Water Systems 11 Wastewater treatment
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Dimensioning of water depth
Clear water layer Separation layer Storage layer Thickening layer XBS Sludge concentration at bottom tth Thickening time 1.5 – 2.0 h without nitrification 1.0 – 1.5 h with nitrification 2.0 – (2.5) h with denitrification ATV A131 (2000) Urban Water Systems 11 Wastewater treatment
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Calculation procedure (plant without nitrogen elimination)
estimate or measure inflow load choose system estimate sludge volume index choose thickening time calculate concentration of bottom sludge calculate return sludge concentration choose recycle ratio estimate XAST calculate surface of secondary clarifier calculate h1, h2, h3, h4 of secondary clarifier check thickening time calculate volume of activated sludge tank is balance between AST and SC optimised? Variation XAST Urban Water Systems 11 Wastewater treatment
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Circular tank With scraper or suction removal device Scum skimmer
Flocculation chamber Sludge scraper Inlet With scraper or suction removal device Urban Water Systems 11 Wastewater treatment
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Rectangular tank, longitudinal flow, flight scraper system
Chain motor Effluent launder Water level Effluent Inlet Sludge Sludge hopper Urban Water Systems 11 Wastewater treatment
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Rectangular tank, lateral flow, suction system
Inlet channel Removal bridge Scum skimmer Inlet baffle Urban Water Systems 11 Wastewater treatment
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Vertical flow tank Effluent launder Effluent Pump Return sludge Inlet
Filter Thickening Return sludge Urban Water Systems 11 Wastewater treatment
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