Presentation is loading. Please wait.

Presentation is loading. Please wait.

In Flexible Slabstock Foams PFA – Pt Clear AL 2007.

Similar presentations


Presentation on theme: "In Flexible Slabstock Foams PFA – Pt Clear AL 2007."— Presentation transcript:

1 In Flexible Slabstock Foams PFA – Pt Clear AL 2007

2 ecomate ® advantages  A LIQUID Physical Blowing Agent  Patented: US 6,753,357 w others [WP] Pending  To Replace Acetone  ENVIRONMENTALLY BENIGN  ZERO ODP, Negligible GWP, VOC Exempt [US EPA]  Excellent Solubility  Less Hazardous to Use

3 ecomate ® Blowing Agent Properties  Clear, Colorless, Flammable Liquid  Boiling Pt  Flash Point  LEL \ UEL  LAMBDA, gas ( 25 °C)  Vapor Pressure ( 25 °C)  Auto Ignition Temp  Specific Gravity  Molecular Weight 88.7 F31,5 C -26 F-32 C 5 - 23% 0.07410,7 11.4 psig586 mm >840 F>450 C 0.9820,982 60

4 ecomate ® Blowing Agent - Environmental Characteristics  ecomate blowing agent is an attractive long term environmental option ODPGWP VOC CFC 1114000NO CFC 1218500NO HCFC 141b0.1630NO HCFC 220.051700NO HCFC 1240.02480NO HCFC 142b0.062000NO HFC 134a01300NO HFC 245fa0790 -1040NO Cyclopentane011YES ecomate0negNO

5 Toxicity U.S.EPA HPV Chemical Challenge Program Revised Test Plan for the Formates Category Formic Acid* CAS#: 64-18-6 Sodium Formate CAS#: 141-53-7 Calcium Formate CAS#: 544-17-2 Methyl Formate CAS#: 107-31-3 Submitted by: American Chemistry Council Formic Acid and Formates Panel Submitted to: U.S. Environmental Protection Agency Prepared by: Elmer Rauckman, PhD, DABT Toxicology and Regulatory Affairs Freeburg IL 62243 May 27, 2003 * Formic Acid is being reviewed as an ICCA chemical and is not formally a HPV chemical. http://www.epa.gov/chemrtk/formates/c13438rt.pdf#search='methyl%20formate'

6 Toxicity  The acute toxicity of all Formate materials is low with NO special hazards  Methyl Formate [MF] is transformed very rapidly into formic acid and methanol in the body with a half-life on the order of several seconds.  Formic Acid is present in many foods (18)  fruit juices (30 -100 ppm),  honey (20 -2000 ppm),  wines (1 -340 ppm),  coffee, roasted (1350 -2200 ppm),  coffee, extracts (2000 -7700 ppm),  evaporated milk (30 -400 ppm), and  cheese (20 -200 ppm) (19). (20). (page 14)  The 4-hour inhalation LC50 of methyl formate was > 21 mg/L  All found negative in the Ames test  No further testing is recommended.

7 Toxicity  The acute toxicity of all Formate materials is low with NO special hazards  Methyl Formate [MF] is transformed very rapidly into formic acid & methanol in the body with a half-life of several seconds.  Formic Acid is present in many foods (18)  fruit juices (30 -100 ppm),  honey (20 -2000 ppm),  wines (1 -340 ppm),  coffee, roasted (1350 -2200 ppm),  coffee, extracts (2000 -7700 ppm),  evaporated milk (30 -400 ppm), and  cheese (20 -200 ppm) (19). (20). (page 14)  The 4-hour inhalation LC50 of MF was > 21 mg/L  All found negative in the Ames test  No further testing is recommended.

8 Effects of Acetone  Long Term Animal Studies  Kidney Damage  Liver Damage  Nerve Damage  Increased Birth Defects  Lowed Reproduction [Males]

9 Use in Foams  Rigid Pour & Spray  Integral Skinned Foams  Flexible

10 Integral Skin

11  ecomate – best alternative to 141b  Solvates all Raws currently used  BPt. just above ambient [like 141b]  Permits good skin formation  Allows fast demold times  Environmentally Benign  Economical – Mol Wt HALF of 141b  US EPA SNAP Approved

12 Flexible Foams Molded & Slab  Good Solubility  Fine Cells  Less Flammable than Hydrocarbons  Non-VOC  Excellent Hand

13 Flexible Foams Molded & Slab EcomateAcetone Mol Wt6058 B Pt, °C32.156.3 LEL, vol% 52.5 UEL, vol% 2312.8 Heat of Vaporization, BTU/Lb 202.3234 PEL, ppm 50001000 TLV, ppm 100 500  Same MW = Same Density  Lower BPt = More Efficient  Lower HtVap = Lower Density  Higher LEL = Lower Hazard  Higher PEL = Lower Hazard  Lower GWP  NO Baggage – Now or Future !

14 Full Scale Trials  2 Seamless Trials  One MDI, one TDI  Both Successes  MDI Trial  Slabstock and Visco-elastic Foam  As Soft or Softer  Reaches ALL density ranges  More Economical

15 TDI SLAB TRIAL  Pre-Trial Methodology  Visitation  Determine Current BA Handling & Exhaust  Consultation - Storage, Transfer, Use  Safely w/o significant changes or expense  Calculation – Max Emissions = 0.27vol%  Set Up - Fully Engineered, work with local Fire Marshall  Inspection - line monitored during run

16 TDI Trials  Two Systems  System X  High Ecomate loading ~ 4.8% of system  Low Density = 0.90 pcf  System Y  Lower Ecomate Loading ~ 1% of system  Higher Thru-put  Low density = 0.95 pcf

17 Ecomate Monitoring TDI Flex SlabstockSYSTEM X SYSTEM Y Foam Thruput, lbs/min 434467 Ecomate Thruput, lbs/min 229.5 Run Time, min 5.85.3 Density, pcf 0.890.96 Trough [% of LEL] 2%1% Blow-off [% of LEL] 1% Side rollers [% of LEL] 1%0% Cut-off saw [% of LEL] 2%0%

18 Trial Foams Y X

19 CONCLUSIONS  INTEGRAL SKIN  ecomate - a perfect fit  solubility,  ideal BPt,  Lo MW,  environmentally benign  SLABSTOCK  All the Above  Less Hazardous than Acetone

20 ecomate ® advantages  A True LIQUID Blowing Agent  Good Solubility  Good Foam Properties  Less Hazardous to USE  Cost Competitive  BENIGN to ENVIRONMENT  No Future Baggage!

21 The Next Generation Blowing Agent


Download ppt "In Flexible Slabstock Foams PFA – Pt Clear AL 2007."

Similar presentations


Ads by Google