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Carpet Waste Gasification: Technical, Economic, Environmental Assessment for Carpet Mills An Interim Presentation ENCH 4300—Capstone UT Chattanooga Jordan Buecker April 12, 2017 Christopher Burns Advisor: Dr. Jim Henry Katharine Davis Hemali Dholakia Kevin O’Brien
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Outline Problem Statement Principle of Gasification Methodology
Proposed Systems Syngas Uses Environmental Analysis Economics Conclusions
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Problem Statement 250 tons per day of post-consumer carpet (PCC)
Currently pay disposal fees Reclaim a portion of the chemical energy from the PCC
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Problem Statement PCC has lower heating value of 8,800 Btu/lb
Bituminous coal LHV = 11,000 Btu/lb Natural gas LHV = 20,000 Btu/lb Gasification Processes PCC considered Produce syngas Syngas LHV = 8,000-12,000 Btu/lb
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Principle of Gasification
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Percentage of Carpet (wt%) Percentage removed pre-gasification (wt%)
Methodology 250 tons/day of post consumer carpet Carpet composition (wt%) Component Percentage of Carpet (wt%) Percentage removed pre-gasification (wt%) Polypropylene (PP) 17 Calcium Carbonate (CaCO3) 35 80 Polyethylene Terephtalate (PET) 6 Nylon 6 (N 6) 100 Nylon 6,6 (N 6,6) 14 Styrene Butadiene Rubber (SBR) 11
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Methodology PP -18600 1700 -32 CaCO3 800 700 0.6 PET -9500 630 -6 SBR
Material Heat of Combustion (BTU/lb) Flowrate (lb/hr) MMBTU/hr PP -18600 1700 -32 CaCO3 800 700 0.6 PET -9500 630 -6 SBR -18900 1100 -21 N66 -13800 1400 -19 Total 79 MM BTU/hr
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Methodology Employed ChemCad modeling software Material balance
Energy balance
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Proposed Systems Air Gasifier
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Proposed Systems Air Gasifier
N2 presence reduces heating value Produces NOx
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Proposed Systems O2 Gasifier
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Proposed Systems O2 Gasifier
Capital increase due to N2 separation Capital decrease due to volumetric flow from the gasifier
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Proposed Systems Steam Gasifier
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Proposed Systems Steam Gasifier
Lower Temperature Produces CH4 (higher heating value syngas)
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Current Syngas Use Current Syngas Use Boiler Exhaust Steam Air Syngas
Plant Use
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Potential Syngas Use Exhaust High Pressure Steam Air Boiler Syngas
Steam Turbine Condensate Low Pressure Steam Condenser
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Potential Syngas Use Low Temp Exhaust High Pressure Steam Boiler
Hot Exhaust Steam Turbine Work Gas Turbine Air Work Syngas
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Energy Recovery Gasifier MM BTU/h BTU/lb PCCW Air 58 5800 O2 Steam 35
3500
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Pollutants Air 14000 240 13% 300 -14% O2 negligible Steam 11000 310
Gasifier lb/h CO2 lb CO2/MM BTU Coal compare lb/h NOx Air 14000 240 13% 300 -14% O2 negligible Steam 11000 310 48%
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Interim Conclusions Technologically and Environmentally Feasible
Economic Analysis will be performed
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Questions We Have What were the strong points?
What can be improved upon? What can be omitted?
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