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Published byMaggie Rickert Modified over 9 years ago
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1 X 2 : NO C 2 : z z = 3/2 = 1/2 Spin-orbit interaction Orbit-rot. interaction z = 3/2 = 1/2 Spin-orbit interaction Orbit-rot. interaction
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E1´E1´ E 1 ´´E 2 ´´ A v´´=0 Orbit-rot. interaction E2´E2´ C v´´=0 C v´ (2,1) (1,2) (1,1) (2,2) A v´ Orbit-rot. interaction
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Energy level expressions used for 2 1/2,3/2 <-<-<- 2 1/2,3/2 : E 1 ´´ = C v´´= 0 + A v´´= 0 + B 1 ´´J´´(J´´+1) – D 1 ´´J´´ 2 (J´´+1) 2 (1a) E 2 ´´ = C v´´= 0 +B 2 ´´J´´(J´´+1) – D 2 ´´J´´ 2 (J´´+1) 2 (1b) E 1 ´ = C v´ + A v´ + B 1 ´J´(J´+1) – D 1 ´J´ 2 (J´+1) 2 (2a) E 2 ´ = C v´ +B 2 ´J´(J´+1) – D 2 ´J´ 2 (J´+1) 2 (2b)
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