1. Solid and Hazardous Waste21
Solid and Hazardous Waste

2. Core Case Study: E-Waste – An Exploding Problem
Electronic waste (e-waste) is the fastest growing solid waste problem
Most ends up in landfills and incinerators
Composition includes:
High-quality plastics
Valuable metals
Toxic and hazardous pollutants

3. Core Case Study: E-Waste – An Exploding Problem (cont’d.)
Shipped to other countries
International Basel Convention
Bans transferring hazardous wastes from developed countries to developing countries
European Union
Cradle-to-grave approach

4. Figure 21-1: These workers in Taizhou City in China’s Zhejiang Province are recovering valuable materials from scrap computers shipped from the United States. Question: Have you disposed of an electronic device lately? If so, how did you dispose of it?
Fig. 21-1, p. 576

5. 21-1 What Are Solid Waste and Hazardous Waste, and Why Are They Problems?
Solid waste contributes to pollution and includes valuable resources that could be reused or recycled
Hazardous waste contributes to pollution, as well as to natural capital degradation, health problems, and premature deaths

6. In the natural world, there is essential no waste because the waste of one organism become nutrients or raw materials for others.
Because of humans we have…

7. We Throw Away Huge Amounts of Useful Things
Solid waste
Any unwanted or discarded material we produce that is not liquid or gas
1. Industrial solid waste
Produced by mines, farms, industries
2. Municipal solid waste (MSW)
Garbage or trash produced by homes and workplaces

8. In more developed countries:
Most waste ends up in:
Rivers, lakes, the ocean, and natural landscapes
In more developed countries:
MSW is buried in landfills or burned in incinerators
In less developed countries:
-open dumps, people use or sell

9. Hazardous Waste Is a Serious and Growing Problem
Hazardous waste (toxic waste)
Any discarded material or substance that threatens human health of the environment
Examples: industrial solvents, hospital medical waste, car batteries, dry-cell batteries, and household pesticide products

10. Classes of hazardous waste
Organic compounds
Various solvents, pesticides, PCBs, and dioxins
Toxic heavy metals
Lead, mercury, arsenic
Radioactive waste
Waste produced by nuclear power plants and nuclear weapon facilities
Must be stored for 10,000 to 240,000 years; have not found safe way to isolate

11. Case Study: Solid Waste in the United States
Leader in solid waste problem
In trash production, by weight, per person
98.5% of all solid waste is industrial waste
1.5% is MSW (Each American throws away 7 pounds of trash every day or 2,750 pounds a year)
Most wastes break down very slowly
If at all

12. Figure 21-5: A year’s worth of solid waste produced by family of four in San Diego, California. Recyclable items are on the left and the rest of their MSW is on the right.
Fig. 21-5, p. 579

13. 21-2 How Should We Deal with Solid Waste?
A sustainable approach to solid waste is:
First to reduce it
Then to reuse or recycle it
Finally, to safely dispose of what is left

14. We Can Burn, Bury, or Recycle Solid Waste or Produce Less of It
1.Waste management
Reduce harm, but not amounts
Typically involves mixing wastes together and then transferring them from one part of the environment to another, usually by burying them, burning them, or shipping them to another location

15. 3.Integrated waste management
2.Waste reduction
Use less and focus on reuse, recycle, compost
3.Integrated waste management
Uses a variety of strategies

16. To manufacturers for reuse or for recycling Compost Landfill
Raw materials
Processing
and manufacturing
Products
Solid and hazardous wastes generated during the manufacturing process
Waste generated
by households
and businesses
Figure 21-6: We can reduce wastes by refusing or reducing resource use and by reusing, recycling, and composting what we discard, or we can manage them by burying them in landfills or incinerating them. Most countries rely primarily on burial and incineration. Question: What happens to the solid waste you produce?
Food/yard waste
Hazardous waste
Remaining mixed waste
Plastic
Glass
Metal
Paper
To manufacturers for reuse or for recycling
Hazardous waste management
Compost
Landfill
Incinerator
Fertilizer
Fig. 21-6, p. 581

17. We Can Cut Solid Wastes by Refusing, Reducing, Reusing, and Recycling
Waste reduction is based on:
Refuse – don’t use it
Reduce – use less
Reuse – use it over and over
Recycle- convert it to useful items and buy products made from recycled materials.

18. Composting
Form of recycling that uses bacteria to decompose yard trimmings, vegetable food scraps, & biodegradable waste into materials that can increase soil fertility.

19. Refusing, Reducing, Reusing, and Recycling (cont’d.)
Six strategies to reduce resource us, waste, and pollution:
1. Change industrial processes to eliminate harmful chemicals
2. Redesign manufacturing process to use less material and energy
3. Develop products that are easy to recycle
4. Eliminate unnecessary packaging
5. Use fee-per-bag waste collection systems
6. Establish cradle-to grave responsibility

20. What We Should Do What We Do Reduce Bury (67%) Reuse
Recycle/Compost (23.7%)
Recycle/Compost
Incinerate (9%)
Incinerate
Reuse (0.2%)
Figure 21-7: Priorities recommended by the U.S. National Academy of Sciences for dealing with municipal solid waste (left) compared with actual waste-handling practices in the United States based on data (right). Question: Why do you think most countries do not follow most of the scientific-based priorities listed on the left?
Bury
Reduce (<0.1%)
Fig. 21-7, p. 581

21. 21-3 Why Are Refusing, Reducing, Reusing, and Recycling So Important?
By refusing and reducing resource use and by reusing and recycling what we use, we:
Decrease our consumption of matter and energy resources
Reduce pollution and natural capital degradation
Save money

22. There Are Alternatives to the Throwaway Economy
We increasingly substitute throwaway items for reusable ones
In general, reuse is on the rise
One solution: taxing plastic shopping bags
Ireland, Taiwan, the Netherlands

23. Figure 21-11: Individuals matter
Figure 21-11: Individuals matter. There are many ways to reuse the items we purchase. Question: Which of these suggestions have you tried and how did they work for you?
Fig , p. 583

24. There Is Great Potential for Recycling
Primary, closed-loop recycling
Materials recycled into new products of the same type
Secondary recycling
Materials converted to other products: tires
Types of wastes that can be recycled
Preconsumer, internal waste generated in manufacturing process
Postconsumer, external waste generated by product use

25. Steps to recycling: 1. collecting materials
2. converting materials to new products
3. selling and buying of products

26. There Is Great Potential for Recycling (cont’d.)
With incentives, the U.S. could recycle and compost 80% of its municipal solid waste
Composting
Mimics nature’s recycling of nutrients
Resulting organic matter can be used to:
Supply plant nutrients
Slow soil erosion
Retain water
Improve crop yield

27. We Can Mix or Separate Household Solid Wastes for Recycling
Materials-recovery facilities (MRFs)
Machines or workers separate mixed waste to recover valuable materials for sale to manufacturers as raw materials.
Source separation
Pay-as-you-throw
Fee-per-bag

28. Recycling Paper Production of paper versus recycled paper
Energy use – world’s fifth largest consumer
Water use
Pollution
Easy to recycle
Uses 64% less energy
Produces 35% less water pollution
Produces 74% less air pollution

29. Recycling Plastics Plastics Currently only 7% is recycled in the U.S.
Composed of resins created from oil and natural gas
Currently only 7% is recycled in the U.S.
Many types of plastic resins making it difficult to separate from products that contain them

30. Recycling Has Advantages and Disadvantages
Net economic health
Environmental benefits
Disadvantages
Costly
Single-pickup system
No separation needed

31. Trade-Offs Recycling Advantages Disadvantages
Reduces energy and mineral use and air and water pollution
Can cost more than burying in areas with ample landfill space
Reduces greenhouse
gas emissions
Reduces profits for landfill and incinerator owners
Figure 21-14: Recycling solid waste has advantages and disadvantages (Concept 21-3). Questions: Which single advantage and which single disadvantage do you think are the most important? Why?
Reduces solid waste
Inconvenient for some
Fig , p. 585

32. 21-4 The Advantages and Disadvantages of Burning or Burying Solid Waste
Technologies for burning and burying solid wastes are well developed
However, burning contributes to air and water pollution and greenhouse gas emissions, and buried wastes eventually contribute to the pollution and degradation of land and water resources

33. Burning Solid Waste Has Advantages and Disadvantages
Waste-to-energy incinerators
Use the heat they generate to boil water and make steam for heating water or for producing electricity
US incinerates about 9% of MSW

34. Electrostatic precipitator
Electricity
Smokestack
Steam
Turbine
Crane
Generator
Furnace
Wet scrubber
Boiler
Electrostatic precipitator
Waste pit
Water added
Figure 21.13: Solutions. A waste-to-energy incinerator with pollution controls burns mixed solid wastes and recovers some of the energy to produce steam to use for heating or producing electricity. Questions: Would you invest in such a project? Why or why not?
Bottom ash
Dirty water
Conveyor
Fly ash
To waste
treatment plant
Ash for treatment, disposal in landfill, or use as landfill cover
Fig , p. 588

35. Waste-to-Energy Incineration
Trade-Offs
Waste-to-Energy Incineration
Advantages
Disadvantages
Reduces trash volume
Expensive to build
Produces a hazardous waste
Produces energy
Concentrates hazardous substances into ash for burial
Figure 21-16: Incinerating solid waste has advantages and disadvantages (Concept 21-4). These trade-offs also apply to the incineration of hazardous waste. Questions: Which single advantage and which single disadvantage do you think are the most important? Why?
Emits some CO2 and other air pollutants
Sale of energy reduces cost
Encourages waste production
Fig , p. 588

36. Burying Solid Waste Has Advantages and Disadvantages
1.Sanitary landfills
About 67% of MSW in US; Consist of compacted layers of waste between clay or foam
Have strong bottom liners and containment systems to prevent leakage

37. 2.Open dumps Widely used in less-developed countries Large pit
Rare in developed countries
Large pit
Sometimes garbage is burned

38. When landfill is full, layers of soil and clay seal in trash Topsoil
Sand
Electricity generator building
Methane storage and compressor building
Clay
Garbage
Leachate
treatment system
Probes to detect
methane
leaks
Pipes collect explosive methane for use as fuel
to generate electricity
Methane gas recovery
well
Leachate storage tank
Compacted solid waste
Figure 21-17: Solutions. A state-of-the-art sanitary landfill is designed to eliminate or minimize environmental problems that plague older landfills. Question: Some experts say that these landfills will eventually develop leaks and could emit toxic liquids. How do you think this could happen?
Garbage
Groundwater monitoring
well
Leachate pipes
Leachate pumped up to storage tank for safe disposal
Sand
Synthetic liner
Leachate monitoring well
Groundwater
Sand
Clay and plastic lining to
prevent leaks; pipes collect leachate from bottom of landfill
Clay
Subsoil
Fig , p. 589

39. Trade-Offs Sanitary Landfills Advantages Disadvantages
Low operating costs
Noise, traffic, and dust
Releases greenhouse gases (methane and CO2) unless they are collected
Can handle large amounts of waste
Filled land can be used for other purposes
Output approach that encourages waste production
Figure 21-18: Using sanitary landfills to dispose of solid waste has advantages and disadvantages (Concept 21-4). Questions: Which single advantage and which single disadvantage do you think are the most important? Why?
No shortage of landfill space in many areas
Eventually leaks and can contaminate groundwater
Fig , p. 589

40. 21-5 How Should We Deal with Hazardous Waste?
A more sustainable approach to hazardous waste:
First, produce less of it
Then, reuse or recycle it
Then, convert it to less-hazardous materials
Finally, safely store what is left

41. We Can Use Integrated Management of Hazardous Waste
Integrated management of hazardous wastes:
1.Produce less
2.Convert to less hazardous substances
3.Rest in long-term safe storage
Increased use for postconsumer hazardous waste

42. Produce Less Hazardous Waste
Change industrial processes to reduce or eliminate hazardous waste production
Recycle and reuse hazardous waste
Convert to Less Hazardous or Nonhazardous Substances
Natural decomposition
Incineration
Thermal treatment
Chemical, physical, and biological treatment
Dilution in air or water
Put in
Perpetual Storage
Landfill
Underground injection wells
Surface impoundments
Underground salt formations
Figure 21-20: Integrated hazardous waste management: The U.S. National Academy of Sciences has suggested these priorities for dealing with hazardous waste (Concept 21-5). Question: Why do you think most countries do not follow these priorities?
Stepped Art
Fig , p. 591

43. Case Study: Recycling E-Waste
70% goes to China
Hazardous working conditions
Includes child workers
U.S. produces roughly 50% of the world’s e-waste
Recycles only 14%

44. We Can Detoxify Hazardous Wastes
Collect and then detoxify
1.Physical methods
2.Chemical methods
3.Use nanomagnets
4.Bioremediation
5.Phytoremediation
Incineration
Using a plasma arc torch

45. Radioactive contaminants
Organic contaminants
Inorganic
metal contaminants
Poplar tree
Indian mustard
Brake fern
Sunflower
Willow tree
Landfill
Oil spill
Figure 21-22: Solutions. Phytoremediation involves using various types of plants that function as pollution sponges to clean up contaminants such as radioactive substances (left), organic compounds (center), and toxic metals (right) from soil and water.
Polluted groundwater in
Decontaminated water out
Polluted leachate
Soil
Soil
Groundwater
Groundwater
Rhizofiltration
Roots of plants such
as sunflowers with
dangling roots on ponds
or in greenhouses
can absorb pollutants
such as radioactive
strontium-90 and
cesium-137 and various organic chemicals.
Phytostabilization Plants such as willow trees and poplars can absorb chemicals and keep them from reaching groundwater or nearby surface water.
Phytodegredation
Plants such as poplars can absorb toxic organic chemicals and break them down into less harmful compounds which they store or release slowly into the air.
Phytoextraction
Roots of plants such as Indian mustard and brake ferns can absorb toxic metals such as lead, arsenic, and others and store them in their leaves. Plants can then be recycled or harvested and incinerated.
Fig , p. 593

46. We Can Store Some Forms of Hazardous Waste
Burial on land or long-term storage
Last resort only; “out of site, out of mind”
Deep-well disposal
Liquid hazardous wastes are pumped under pressure through a pipe into dry, porous rock formations
64% of hazardous liquid wastes in the U.S.
Surface impoundments
Lined ponds, pits, or lagoons in which liquid hazardous wastes are stored

47. Secure hazardous waste landfills
Expensive; both liquid and solid hazardous wastes are put into drums or other containers and buried

48. Trade-Offs Deep-Well Disposal Advantages Disadvantages
Safe if sites are chosen carefully
Leaks from corrosion of well casing
Emits CO2 and other air pollutants
Wastes can often be retrieved
Figure 21-24: Injecting liquid hazardous wastes into deep underground wells has advantages and disadvantages. Questions: Which single advantage and which single disadvantage do you think are the most important? Why?
Output approach that encourages waste production
Low cost
Fig , p. 594

49. Trade-Offs Surface Impoundments Advantages Disadvantages
Low cost
Water pollution from leaking liners and overflows
Wastes can often be retrieved
Air pollution from volatile organic compounds
Figure 21-26: Storing liquid hazardous wastes in surface impoundments has advantages and disadvantages. Questions: Which single advantage and which single disadvantage do you think are the most important? Why?
Can store wastes indefinitely with secure double liners
Output approach that encourages waste production
Fig , p. 594

50. Figure 21-28: Individuals matter
Figure 21-28: Individuals matter. You can reduce your output of hazardous wastes (Concept 21-5). Questions: Which two of these measures do you think are the most important ones to take? Why?
Fig , p. 595

51. Case Study: Hazardous Waste Regulation in the United States
1976 – Resource Conservation and Recovery Act (RCRA)
EPA sets standards and gives permits
Cradle to grave
Covers only 5% of hazardous wastes

52. Case Study: Hazardous Waste Regulation in the United States (cont’d.)
1980 – Comprehensive Environmental, Compensation, and Liability Act (CERCLA)
National Priorities List
2013 – 1320 Superfund sites; 365 cleaned
Pace of cleanup has slowed
Superfund is broke
Laws encouraging the cleanup of brownfields
Abandoned industrial sites

53. Figure 21-29: Leaking barrels of toxic waste found at a Superfund site that has since been cleaned up.
Fig , p. 596

54. 21-6 How Can We Make the Transition to a More Sustainable Low-Waste Society?
Shifting to a low-waste society requires individuals and businesses to:
Reduce resource use
Reuse and recycle wastes at local, national, and global levels

55. Grassroots Action Has Led to Better Solid and Hazardous Waste Management
Prevent construction of:
Incinerators, landfills, treatment plants, polluting chemical plants
Something must be done with hazardous wastes
Apply precautionary principle

56. Providing Environmental Justice for Everyone Is an Important Goal
Everyone is entitled to protection from environmental hazards
Communities in the U.S. have the largest share of hazardous waste dumps:
African American, Asian American, Latinos, and Native American
Environmental discrimination has led to environmental justice movement

57. We Can Encourage Reuse and Recycling
Factors that hinder reuse and recycling:
1.Market prices do not include harmful costs
2.Economic playing field is uneven
3.Demand for recycled products fluctuates
Governments can pass laws requiring companies to reuse and recycle

58. Reuse, Recycling, and Composting Present Economic Opportunities
1. Freecycle network
2. Upcycling
Recycling materials into products of higher value
3. Dual-use packaging

59. International Treaties Have Reduced Hazardous Waste
Basel Convention
1992 – in effect
1995 amendment – bans all transfers of hazardous wastes from industrialized countries to less-developed countries
2012 – ratified by 179 countries, but not the United States

60. International Treaties Have Reduced Hazardous Waste (cont’d.)
2000 – delegates from 122 countries completed a global treaty
Control 12 persistent organic pollutants (POPs)
Include DDT, PCBs, dioxins
Discovered that everyone on earth has POPs in blood
2000 – Swedish Parliament law
By 2020 ban all chemicals that are persistent and can accumulate in living tissue

61. We Can Make the Transition to Low-Waste Societies
Norway, Austria, and the Netherlands
Committed to reduce resource waste by 75%
Key principles
1.Everything is connected
2.There is no away
3. Producers and polluters should pay for their wastes
4. We can mimic nature by reusing, recycling, composting, or exchanging MSW we produce

62. Case Study: Industrial Ecosystems: Copying Nature
Resource exchange webs
Waste as raw material
Ecoindustrial parks
Two major steps of biomimicry
Observe how natural systems respond
Apply to human industrial systems

63. Three Big Ideas
The order of priorities for dealing with solid waste should be to:
Produce less of it
Reuse and recycle as much of it as possible
Safely burn or bury what is left

64. Three Big Ideas (cont’d.)
The order of priorities for dealing with hazardous waste should be to:
Produce less of it
Reuse or recycle it
Convert it to less hazardous material
Safely store what is left

65. Three Big Ideas (cont’d.)
View solid wastes as wasted resources, and hazardous wastes as materials that we should not be producing in the first place

66. Tying It All Together: E-Waste and Sustainability
Reduce outputs of solid hazardous waste
Mimic nature’s chemical cycling process
Reuse and recycle
Integrated waste management
Include harmful environmental and health costs in market prices