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The Physical Properties Of Minerals
WJEC AS Geology I.G.Kenyon
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Colour 1 Determined by the chemical composition of the mineral
8cm Determined by the chemical composition of the mineral Minerals rich in Al, Ca, Na, Mg, Ba and K are often light coloured Minerals rich in Fe, Ti, Ni, Cr, Co, Cu and Mn are often dark in colour Haematite, Kidney Ore
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Colour 2 Determined by the atomic structure of the mineral
5cm Determined by the atomic structure of the mineral Atomic structure controls which components of white light are absorbed or reflected White minerals reflect all components of white light Black minerals absorb all components of white light Green minerals reflect green light and absorb the others Pyrite Cubes with Striated Faces
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Colour 3 Colour is not particularly useful as a diagnostic property
Some minerals show a wide variety of colours Quartz can be transparent, white, pink, brown, purple, yellow, orange and even black Many minerals show very similar colours Calcite, gypsum, barytes, fluorite, plagioclase feldspar and halite are commonly grey or white in colour
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Examples of colour variation in Fluorite
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Colour 5 All these minerals are grey or white in colour
Plagioclase feldspar Quartz Calcite Barytes Fluorite Gypsum All these minerals are grey or white in colour
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Transparency 2cm When outlines of objects seen through it appear sharp and distinct A good examples is Iceland Spar, a variety of calcite that is used for optical lenses Iceland Spar also shows the remarkable property of double refraction Determined by the atomic structure and chemical composition of the mineral Calcite – Iceland Spar
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Translucency 1 cm The ability for a mineral to let light pass through it Many minerals if cut thin enough will show some degree of translucency Controlled by atomic structure and chemical composition All transparent minerals are also translucent Fluorite
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Lustre Quartz – Vitreous Lustre
The way in which a mineral reflects light Controlled by the atomic structure of the mineral Main types of lustre are Vitreous Metallic Pearly Resinous Adamantine Dull/Earthy 2cm Quartz – Vitreous Lustre
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Vitreous Lustre Dog-Tooth Calcite Fluorite
The mineral reflects light like glass Sometimes glassy lustre is used instead of vitreous
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Metallic Lustre Minerals reflect light like metals.
Malachite Galena Minerals reflect light like metals. Metallic lustre often tarnishes to a dull lustre
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Pearly Lustre The lustre of a pearl or mother of pearl
Biotite Mica The lustre of a pearl or mother of pearl Shows clearly on the cleavage surfaces of biotite and muscovite mica Also shown by Talc and selenite (a variety of gypsum) Muscovite Mica
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Silky Lustre The lustre of silk
1cm The lustre of silk Occurs in minerals with a fibrous structure Satin spar (a fibrous form of gypsum) shows this to good effect Gypsum (Satin Spar)
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Resinous Lustre The lustre of resin
1cm The lustre of resin The mineral has a grainy appearance Sphalerite, opal and amber show resinous lustre Sphalerite (Zinc Blende)
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Adamantine Lustre The lustre of a diamond
5mm The lustre of a diamond
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Limonite has a dull or earthy lustre
The mineral does not reflect light and has the same appearance as soil. Minerals such as galena have metallic lustres on freshly broken surfaces but they tarnish to dull with prolonged exposure to the atmosphere 1cm Limonite has a dull or earthy lustre
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Streak The colour of a mineral’s powder
Obtained by rubbing a mineral specimen on an unglazed white porcelain tile Useful for identifying metallic ore minerals Silicates generally do not mark the tile and have no streak White minerals streaked on a white tile will have a white streak Any minerals harder than the tile (6) will scratch it Haematite gives a cherry red streak
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Streak 2 Malachite – pale green Haematite – cherry red
Iron Pyrite – greenish black Galena – lead grey Sphalerite – pale brown Limonite – yellowish brown
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Metallic Ore Minerals – Characteristic Streaks
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Relative Density Measured relative to an equal volume of distilled water at 4 degrees centigrade litre = 1000g (1kg) 1 cubic centimetre = 1g Controlled by the atomic weight of the constituent atoms (chemical composition) and the packing (atomic structure) A useful property for identifying metallic ore minerals, these usually have relative densities over 5.0. The only non-metallic mineral which is quite dense is barytes (4.5) Most of the silicate minerals have densities between 2.5 and 3.2
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Relative Density- Some Examples
Kyanite Gold Fluorite 3.2 Iron Pyrite Haematite Gypsum 2.3
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Measured on Moh’s scale from 1.0 (softest) to 10 (hardest)
Hardness Measured on Moh’s scale from 1.0 (softest) to 10 (hardest) Scale was devised by measuring the amount of noise and powder produced from rubbing a mineral on a metal file Talc 1.0 Diamond 10.0
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Moh’s Scale of Hardness Note diamond is over 30 x harder than corundum
8 Topaz 7 Quartz 6 Orthoclase Feldspar Note diamond is over 30 x harder than corundum
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Moh’s Scale of Hardness
10. Diamond 9. Corundum 8. Topaz 7. Quartz 6. Orthoclase Feldspar
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From 1 through to 9 on the scale, hardness increases in equal steps
Moh’s Scale of Hardness 5 Apatite 4 Fluorite 3 Calcite 2 Gypsum 1 Talc From 1 through to 9 on the scale, hardness increases in equal steps
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Moh’s Scale of Hardness
5. Apatite 4. Fluorite 3. Calcite 2. Gypsum 1. Talc
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Moh’s Scale of Hardness
Steel nail Fingernail 2.5 Copper coin 3.0 Window glass 5.0 Everyday objects can be substituted for minerals on Moh’s scale
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Testing For Hardness Try to scratch mineral specimens with substances of known hardness If a mineral is not scratched by your fingernail, but is scratched by a copper coin then it will have a hardness of 2.5–3.0 If a mineral cannot be scratched by steel it has a hardness of over 6.0 Gypsum is scratched by a fingernail, hardness <2.5
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Mineral Hardness Smaller atoms/ions promote greater hardness in minerals generally Minerals with large ions such as carbonates and sulphates are soft Atomic structure and bond type also control hardness. Covalent bonds are generally stronger than ionic ones Hardness should not be confused with difficulty of breaking-a hard mineral may be very brittle Graph to illustrate difference between Moh’s Scale and Knoop numbers
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The way a mineral breaks when struck by a hammer
Fracture The way a mineral breaks when struck by a hammer The type of fracture is not controlled by any weaknesses in the atomic structure of the mineral
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Types of Fracture Conchoidal – Like Glass Even – Flat fracture surface
Uneven – Irregular fracture surface Hackly – Very jagged like cast iron Fracture is only described when the mineral has no cleavage
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Conchoidal Fracture This type of fracture is the same as that shown by window glass A series of concentric curved lines can be seen on the fractured surface A diagnostic property of the mineral quartz 5mm Rose quartz showing conchoidal fracture
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Cleavage The way a mineral breaks when struck by a hammer
Cleavage is controlled by lines of weakness in the atomic structure of the mineral Minerals can have 1, 2, or 4 planes of cleavage 1 plane, parallel or basal cleavage 2 planes of cleavage that intersect at a characteristic angle 3 planes (cubic, rhombohedral) 4 planes, octahedral cleavage
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Parallel or Basal Cleavage
1cm 1cm Barytes Biotite Mica One plane of cleavage enables the mineral to part along parallel lines. It is analogous to a ream of paper that can be separated into individual sheets.
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Minerals Showing 2 Sets of Cleavage Planes
1cm 1cm Augite Plagioclase Feldspar Feldspars – intersect at 90 degrees Augite (Pyroxene) – intersect at 90 degrees Hornblende (Amphibole) – Intersect at 60/120 degrees
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Prismatic Cleavage 1cm Produced by the intersection of three cleavage planes Cubic cleavage 3 planes intersect at 90 degrees e.g. halite Rhombohedral cleavage 3 planes intersect at 60/120 degrees e.g. calcite Halite 1cm Calcite
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Cleaved edge of cubic crystal
Octahedral Cleavage Cleaved edge of cubic crystal Fluorite shows well developed octahedral cleavage The cubic crystals are truncated across their corners at 45° by four cleavage planes This can eventually lead to the formation of octahedrons from the original cubic crystals 1cm Cleavage Surface Octahedron
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Acid Reaction Use dilute hydrochloric acid to test for carbonates
Calcite effervesces (fizzes) and gives off carbon dioxide gas Calcite reacting and giving off carbon dioxide 2cm
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Taste If a mineral can be tasted in the mouth, then it is soluble in fresh water Halite (rock salt) tastes salty and is a diagnostic property of the mineral
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Striking Fire With Steel
Iron Pyrite (Fools Gold) sparks when struck with a steel hammer and releases a sulphurous odour Iron Pyrite was used as flints in flintlock pistols to ignite the gunpowder Pyritohedrons Pyrite cubes
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Magnetism 1cm Steel pins and magnet attracted to magnetite
Octahedral crystals of Magnetite The ability of a mineral to attract iron filings and pick up steel pins Magnets stick to magnetite quite readily and is the only strongly magnetic mineral found at the earth’s surface
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Talc feels very greasy when rubbed between the fingers
A characteristic sensation experienced when a mineral is held and rubbed between the fingers 2cm 2cm Graphite feels very cold upon the touch as it is a very good conductor of heat Talc feels very greasy when rubbed between the fingers
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Schiller Effect or Iridescence
The mineral shows a ‘play of colours’ on the surface–similar to the effect of oil/petrol spills in water Produced by the scattering of light by fine planar zones of compositional variation called exsolution lamellae Example labradorite, a common variety of plagioclase feldspar 2cm
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Amorphous Chalcopyrite Crystallised Iron Pyrite
Form or Habit Amorphous Chalcopyrite Crystallised Iron Pyrite This refers to the common appearance of the mineral and varies from crystallised to amorphous or massive
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Variations in Habit/Form/Appearance of Minerals
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Variations in Habit/Form/Appearance of Minerals
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Habit – Botryoidal/Mammilated
The specimen has spherical; lumps or mounds encrusting the surface Botryoidal – the lumps or mounds are less than 2mm in diameter Mammilated – the lumps or mounds are over 2mm in diameter (‘breast-like’) 1cm Mammilated Haematite
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Habit – Stalactitic, Fibrous and Radiating
1cm 2cm Haematite showing stalactitic form with fibrous and radiating internal structure
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Habit - Acicular Kyanite Chiastolite
The mineral occurs as thin needle-like crystals Examples chiastolite, tourmaline, andalusite and kyanite 2cm 2cm Kyanite Chiastolite
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Rhombdodecahedral Garnet Crystals
Habit - Crystallised 1 cm Rhombdodecahedral Garnet Crystals
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Habit – Nodular, Fibrous and Radiating
1cm Iron Pyrite showing nodular habit with fibrous and radiating internal structure
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Habit – Foliate/Lamellar Muscovite Mica showing foliate/lamellar habit
1cm Muscovite Mica showing foliate/lamellar habit
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Tabular mass of Barytes crystals
Habit - Tabular 1cm Tabular mass of Barytes crystals
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Randomly oriented barytes crystals up to 8cm long
Habit - Bladed 2cm Randomly oriented barytes crystals up to 8cm long
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Habit - Reticulate 1cm Interlocking framework structure resembling a delicate snowflake shown by Cerussite from Tsumeb, Namibia
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Habit – Dendritic/Arborescent
Manganese oxide dendrites on limestone, Solnhofen, Germany
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Diagnostic Properties
Those properties that allow any mineral to be identified Most minerals have two to four diagnostic properties Hardness, cleavage, streak and habit are most useful Colour, lustre, transparency and density are less useful Special properties such as acid reaction, taste, magnetism, striking fire with steel and feel are often used to identify a mineral
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The End
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