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Inclusions in gemstones: Gems in Gems
Egor Gavrilenko Instituto Gemológico Español
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Inclusions in gemstones: Gems in Gems
Introduction Types of inclusions Importance of inclusions: In Geology In Gemology Methods of inclusion’s studies The artistic side of inclusions: Photomicrography Special cuts and jewelry
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Introduction Inclusions: Particles of other minerals or cavities found inside crystals, trapped during crystal’s growth or formed inside after the host mineral formation. In gemology, are also considered mechanical inclusions (fissures, growth lines, etc.) and color zoning, described together as “internal characteristics” of gems.
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Introduction Negative impact on quality of gemstones (Clarity)
Photos Anthony Cáceres
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Types of inclusions: By type of trapped material
Single phase: Solid Liquid Gaseous Two phases: Liquid-vapor Liquid-liquid Liquid-solid Solid-gaseous Three phases … Multiphase …. Photo Juan S. Cózar
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Types of inclusions: By time of their formation
For solid inclusions Protogenetic Syngenetic Epigenetic For fluid inclusions Primary Secondary Pseudo-secondary
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Applications in Geology
Sequence of mineral formation in mineral deposits P-T conditions of mineral formation (fluid inclusions study, thermodynamic stability diagrams for syngenetic minerals) Development of genetic models for mineral deposits (mineralization fluids origin, age, relation with magmatic and tectonic events, etc.).
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Importance for Gemology
Aesthetic importance Importance for gem’s identification Special collections
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Importance for Gemology
Aesthetic importance: Color of some gems Special phenomena: Aventurescence Chatoyancy Asterism Special gemological varieties Photo Marco Campos Venuti Photo Marco Campos Venuti
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Importance for Gemology
Importance for gem identification: Type of gem Natural or synthetic Treatments Geographic origin Photo José María Alonso Photo Juan S. Cózar Photo José María Alonso
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Methods of inclusions studies
Microscopic observation + photomicrography Electron microscopy + EDX or WDX (punctual) X-ray Fluorescence Spectroscopy (global) Raman Spectroscopy (punctual or global) FTIR Spectroscopy (punctual or global) Fluid inclusions microthermometry
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Methods of inclusions studies
Microscopic observation + photomicrography Electron microscopy + EDX or WDX (punctual) X-ray Fluorescence Spectroscopy (global) Raman Spectroscopy (punctual or global) FTIR Spectroscopy (punctual or global) Fluid inclusions microthermometry
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Fluid inclusions microthermometry
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Emeralds from the Urals
T = oC, P = 2,5-3 kb, 8 wt % NaCl H2Oliq vol % CO2liq ~ 5-7 vol % Vapor vol % TmCO2= Tmice= Tmclatr= Th(LV)CO2= Th(VL)liq
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The artistic side of inclusions
Photomicrography Special cut gems to highlight the beauty of inclusions Designer jewelry focused on gems with inclusions
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Special cut gems John Bailey, www.gemstoneartist.com
Quartz with phantom planes oriented to reflect as "angel wings" John Bailey, Oregon Sunstone using copper schiller to highlight concave faceting John Bailey, “The Sword In the Stone” - quartz with single brookite inclusion John Bailey, Red Hematite flake in Quartz. Flake oriented to give color to the gem. Richard P. Homer, Gems by Design, Inc., Kent, OH, USA 30.95 ct. rutilated Quartz with a single natural needle in the center. AGTA Spectrum Awards Winners 2012 Honorable Mention, Innovative Faceting
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Custom made jewelry White gold pendant with quartz with epidote inclusions and green tourmalines, by Laura Márquez White gold pendant with rutilated quartz and citrines, by Laura Márquez Pendant with rutilated quartz in white gold, by Laura Márquez Quartz with tourmaline needles, cut by Munsteiner, white gold pendant by Laura Márquez Gold neclace with rutilated quartz, by Xisco Clapés Triviño
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