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Acids, Bases and Salts Mrs Teocc
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Acids Acids Strong acids Weak acids man-made mineral acids corrosive
e.g. sulphuric acid hydrochloric acid nitric acid Weak acids found in plants and animals, used in food organic acid not very corrosive e.g. ethanoic acid citric acid malic acid
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Physical Properties of Acids
1. Acids have a taste. sour Lemons, limes, oranges, grapefruits - citric acid Grapes – tartaric acid
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Physical Properties of Acids
2. Acids can the colour of indicators change Indicator Colour in acid Blue Litmus Phenolphthalein Methyl orange Red Colourless Red
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Chemical Properties of Acids
An acid reacts with a metal to form a salt and hydrogen acid + metal salt + hydrogen e.g 1. zinc + hydrochloric acid 2. Magnesium + sulphuric acid zinc + hydrogen chloride Zn HCl ZnCl H2 zinc + hydrogen sulphate Mg + H2SO MgSO H2
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Chemical Properties of Acids
acid + metal salt + hydrogen
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Chemical Properties of Acids
acid + metal salt + hydrogen Note: 1. Different metals have different rates of reaction with dilute acids. 2. Sodium , potassium, lithium react explosively with dilute acids. 3. Copper, silver, gold do not react with dilute acids.
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Chemical Properties of Acids
a salt + water 2. An acid reacts with a base to form acid base salt + water e.g. (a) copper(II) + sulphuric oxide acid (b) sodium hydrochloric hydroxide acid copper(II) + water sulphate CuO H2SO4 CuSO H2O sodium + water chloride HCl NaOH NaCl H2O
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Chemical Properties of Acids
The reaction between a base and an acid to produce a salt and water is called neutralisation.
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Chemical Properties of Acids
3. An acid reacts with a carbonate to produce a salt, water and carbon dioxide acid + carbonate salt + water + carbon dioxide eg. (a)magnesium +hydrochloric carbonate acid magnesium + water + carbon chloride dioxide MgCO HCl MgCl H2O CO2
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Chemical Properties of Acids
carbonate + acid salt + water + carbon dioxide White precipitate is formed
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Properties of Acids Summary 1. Acids have a sour taste.
2. Acids change the colour of indicators 3. acid + metal 4. acid + base 5. acid + carbonate salt + hydrogen salt + water salt + water +carbon dioxide
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Explanation for Properties
1. When an acid dissolves in water, it undergoes ionisation. H+ ions and the corresponding acid polyatomic ions are formed. The properties of an acid are due to the presence of hydrogen ions.
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Hydrogen ions and Acids
citric acid water (hydrogen citrate) sulphuric acid water (hydrogen sulphate) hydrochloric acid + water (hydrogen chloride) H+ ion + citrate ion H+ ion + sulphate ion H+ ion + chloride ion When acid dissolves in water, H+ ions are formed
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Hydrogen ions and Acids
An acid is a substance that produces hydrogen ions in water
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Strength of Acids Acids Strong acids Weak acids
all the acid molecules ionise to become ions Weak acids most molecules remained unchanged
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Some Uses of Acids Hydrochloric acid Sulphuric acid Nitric acid
Cleaning metallic surfaces before they are painted or coated with other metals Used as an in car batteries, making fertilisers, and plastics Making fertilisers and explosives Preserving food and cooking Making health salts Hydrochloric acid Sulphuric acid Nitric acid Ethanoic acid Citric acid
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Bases and Alkalis Bases
* aqueous ammonia * metal oxides and metal hydroxides e.g. copper (II) oxide, zinc oxide, magnesium oxide, sodium oxide, zinc hydroxide, potassium hydroxide Alkalis * aqueous ammonia * metal hydroxides which are soluble in water e.g. calcium hydroxide, sodium hydroxide, potassium hydroxide
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Bases and Alkalis BASES ALKALIS e.g. NaOH
e.g.CuO ALKALIS e.g. NaOH Alkalis are bases but not all bases are alkalis
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Physical of Properties of Alkalis
Alkalis feel Alkalis taste soapy. bitter.
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Physical of Properties of Alkalis
3. Alkalis change the colour of indicators Indicator Colour in Alkali Red litmus Blue Phenolphthalein Pink Methyl Orange Yellow
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Chemical Properties of Alkalis
1. An alkali reacts with an acid to produce a salt and water only. acid + alkali salt + water e.g. (a) copper(II) + sulphuric oxide acid (b) sodium + hydrochloric hydroxide acid copper(II) +water sulphate CuO H2SO4 CuSO H2O sodium + water chloride HCl NaOH NaCl H2O
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The reaction between an alkali (base) and an acid to produce a salt and water is called
neutralisation.
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Chemical Properties of Alkalis
2. An alkali reacts with an ammonium aalt to produce a salt, water and ammonia gas. alkali + ammonium salt salt + water + ammonia gas e.g. ammonium chloride + sodium hydroxide sodium chloride + water + ammonia NH4Cl + NaOH NaCl + H2O + NH3
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Chemical Properties of Alkalis
3. An alkali reacts with a solution of metal salt to form a metal hydroxide. e.g. FeCl NaOH Fe(OH) NaCl (red-brown ppt) CuSO NaOH Cu(OH) Na2SO (blue ppt)
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salt + water + ammonia gas.
Properties of Alkalis Summary 1. Alkalis feel soapy. 2. Alkalis change the colour of indicators 3. alkali + acid 4. alkali + ammonium salt 5. alkali + solution of metal salt salt + water. salt + water + ammonia gas. metal hydroxide + salt
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Hydroxide ions and Alkalis
When an alkali dissolves in water hydroxide ions (OH-) ions are produced. e.g NaOH Na OH KOH K OH- * Properties of alkalis are due to the presence of hydroxide ions.
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Strength of Alkalis Alkalis Strong alkalis Weak alkalis
when the alkali is dissolved in water, all the ions are dissociated Weak alkalis most molecules remained unchanged
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Strength of Alkalis Strong alkalis e.g. NaOH Na+ + OH-
KOH K OH-
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Strength of Alkalis Strong alkalis e.g. NaOH Na+ + OH-
KOH K OH- OH- Na+ OH- Na+ Na+ OH- OH- Na+
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Strength of Alkalis Weak alkalis e.g. NH3 + H2O NH4+ + OH-
- Only a small fraction of ammonia molecules form OH- - Most of molecules remained unchanged
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Strength of Alkalis Weak alkalis e.g. NH3 + H2O NH4+ + OH-
- Only a small fraction of ammonia molecules form OH- - Most of molecules remained unchanged NH3 NH3
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Uses of bases/alkalis mainly for 2 reasons neutralise acids
e.g. toothpaste (magnesium hydroxide) antacid (aluminium hydroxide, magnesium hydroxide) remove grease e.g. soap, floor cleaners (strong alkali-sodium hydroxide) cleaners for glass windows (weak alkali/ /ammonia)
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Uses of Alkalis Alkalis Common names Uses
Sodium hydroxide caustic soda Making soap, washing powder, drain cleaner Potassium hydroxide caustic potash Making paint removers dyes for fabric Calcium hydroxide slaked lime Reducing acidity of soil and making mortar Aqueous ammonia Making fertilisers and (Ammonia solution) household cleaning liquids
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