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Published bySabrina Berriman Modified over 9 years ago
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Objectives
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Free radical chlorination or bromination of alkanes gives a complex 287 Haloalkanes and Haloarenes mixture of isomeric mono- and polyhaloalkanes, which is difficult to separate as pure compounds. CH 4 + Cl 2 CH 3 Cl + HCl Halogenation
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Mechanism Propagation Termination
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Features of Halogenation F 2 > Cl 2 > Br 2 > I 2. Attack of or on an alkane is selective Order of reactivity is 3° > 2° > 1°
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Features of Halogenation
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Isomerization
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By electrophilic substitution Aryl chlorides and bromides can be easily prepared by electrophilic substitution of arenes with chlorine and bromine respectively in the presence of Lewis acid catalysts like iron or iron(III) chloride.
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Alkyl iodides are often prepared by the reaction of alkyl chlorides/ bromides with NaI in dry acetone. This reaction is known as Finkelstein reaction. Halogen Exchange
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Swarts reaction The synthesis of alkyl fluorides is best accomplished by heating an alkyl chloride/bromide in the presence of a metallic fluoride such as AgF, Hg 2 F 2, CoF 2 or SbF 3. The reaction is termed as Swarts reaction.
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