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Organic Chemistry AP Chapter 25
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Properties of Organic Acids Usually have low melting points (below 300 ° C) Usually are non-polar (unless they contain functional groups) and are insoluble in water. Usually are non-conductors of electricity. Can be solid, liquid or gas. – 1-4 carbons tend to be gaseous at room temp. – 5-10 carbons tend to be liquids (gas, solvents) – 12-18 carbons (jet fuels, kerosene) – Above 18 carbons are solids.
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Hydrocarbons from Petroleum
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ethanol propane
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Polymers Made up of many repeating units called monomers. Plastics are polymers made up of crude oil. Polyethylene – many ethene (ethylene) groups linked together (plastic grocery bags, bottles) Polystyrene, (CD cases, and with CO 2 - styrofoam cups)
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Hydrocarbons A hydrocarbon is any chemical that consists of only carbon and hydrogen. They all contain a carbon backbone, called a carbon skeleton.
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Types of Hydrocarbons Alkanes – single bonds between the carbon atoms Alkenes – double bonds between the carbon atoms Alkynes – triple bonds between the carbon atoms Aromatic hydrocarbons – contain at least one benzene ring.
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Alkanes Alkanes are saturated hydrocarbons – contain only single bonds. butane
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Naming Organic Compounds Locate the longest straight chain of carbons to count the number of carbons.
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Cycloalkanes Alkanes that form rings or cycles.
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Alkenes Unsaturated hydrocarbons that contain at least one C=C bond. The naming system follows the IUPAC system.
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Alkynes Unsaturated hydrocarbons that contain at least one triple bond between carbons.
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Addition Reactions These occur in alkenes and alkynes.
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Aromatic Hydrocarbons
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Adding hydrogen to form a saturated compound (hydrogenation)
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Organic Functional Groups Functional groups are sites located on hydrocarbons that are responsible for the reactions that they undergo.
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Alcohols
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Ethers Contain the C – O – C functional group
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Aldehydes
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Ketones
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Organic Acids Also called carboxylic acids and are made by oxidizing alcohols with an aldehydes.
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Esters Carboxylic acids can undergo condensation reactions with alcohols to form esters.
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