1. 2. Compliance with Standards Process Safety Management for Bioethanol This material was produced under grant SH-19479-09-60-F-36 from the Occupational Safety and Health Administration, U.S. Department of Labor. It does not necessarily reflect the views or policies of the U.S. Department of Labor, nor does mention of trade names, commercial products, or organizations imply endorsement by the U.S. Government.

2. Fires in the ethanol industry

3. Flashpoint of Ethanol 55 °F

4. OSHA 1910.106

5. OSHA 1910.119 http://www.osha.gov/pls/oshaweb/owadisp.show_document?p_ta ble=STANDARDS&p_id=9760 Process Safety Regulations

6. Material Safety Data Sheet (MSDS) OSHA 1910.1200 requires that you have an MSDS for every hazardous chemical at your plant. CCPS encourages you to obtain several MSDS’s from the Web and compare that with the MSDS you received from your supplier.

7. NFPA Diamond

8. NFPA Diamond for Ethanol 1 1 Slightly toxic 2 Moderately toxic 3 Seriously toxic or suspected small animal carcinogen, mutagen or teratogen. 4 Extremely toxic or known or suspected human carcinogen

9. NFPA Diamond for Ethanol 3 1 Slightly flammable 2 Moderately flammable 3 Seriously flammable 4 Extremely flammable

10. Avoid Open Flames

11. Avoid static sparks

12. Grounding Bonding Bonding and Grounding

13. NFPA Diamond for Ethanol 0

14. 3 01

15. Use ATC foam for ethanol fires

17. Imperial Sugar

18. Corn Dust Is Explosive

19. Grain Dust Explosions

20. Avoid Dust Accumulation

21. Provide access to all hidden areas

22. Explosion Proof Vacuum

23. ------------------------------------------------------------------------------------- Relief Valve Location

24. Written checklists

25. Remaining Course Material 1.Overview of Process Safety 2.Compliance with standards 3.Process Hazard Analysis 4.Standard Operating Procedures 5.Safe work Procedures 6.Mechanical Integrity 7.Management of Change 8.Auditing Process Safety systems 9.Emergency response procedures