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Review
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Various models of the atom Dalton’s – “billiard ball” model Thomson – “raisin bun” model Rutherford – “Electron Cloud” model Bohr – best model to date
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Molecular Elements Elements ending in –gen are diatomic. Pg. 33 – should know this table
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Changes Pg. 47
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Classifying Chemical Reactions Pg. 58
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Significant Digits Precision is the place value of the last measurable digit and is determined by the instrument 12.0 g vs 12 g vs 10 g Non-zero numbers are significant Zeros to the left are not significant Zeros to the right are significant
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Compounds Valence Electrons Lewis Symbols Electronegativity Types of Bonds Bonding Capacities
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Pg. 88
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Predicting Shape Summary
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Rules of polar and nonpolar
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Electronegativity Differences Pg. 100
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Summary Intermolecular forces are the attraction and repulsion of positive and negative charges All molecules have London forces – with momentary diploes Polar molecules have dipole-dipole forces Hydrogen bonding occurs when a hydrogen is attracted to the lone pair from an adjacent molecule IMF affect many various physical properties
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Physical properties While solid has definite shape and volume; it does have various other properties that can be very different. Such as density, colour, melting points, etc Pg. 119
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Summary
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Unit Test Review Summary Lewis Formulas Bonding Theory (types) Electronegativity Molecular Formulas (Lewis, structural, sterochemical) Bonding capacity VSEPR Bond and molecular Polarity Intermolecular Forces – Isoelectronic Compounds Boiling points Properties of Liquids and Solids
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Units Pg. 149
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Summary STP: 0 ˚ C and 101.325 kPa SATP: 25 ˚ C and 100. kPa 101.325 kPa = 1 atm = 760 mm Hg T (K) = t ( ˚ C) + 273 P 1 V 1 = P 2 V 2 V 1 / T 1 = V 2 / T 2
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Properties of Gases Kinetic molecular theory explains a lot about the properties of gases – Gases are compressible - the distance between the molecules – Gas pressure – the amount of collisions that occur – Boyle’s Law – Charles’ Law
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Ideal Gas Law
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Solvent and Solute Solvent – The component of the solution present in greater amount. Solvent dissolves the solute Solute – The component of the solution present in lesser amount. The solute is dissolved by the solvent.
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Acids and Bases PG 199
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Summary
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Strength of Acids Strong Acids: ionize (splits up into ions) almost 100% in water mostly ions in solution amount of HCl present is negligeable HCl(aq) H + (aq) + Cl - (aq) Weak acids: ionize poorly in water not many of these ions present in solution mostly acetic acid (HC 2 H 3 O 2 ) HC 2 H 3 O 2 (aq) C 2 H 3 O 2 - (aq) + H + (aq) NOTE: strong acids are strong electrolytes and will conduct electricity better than weak acids.
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pH < 7 acidic pH = 7 neutral pH > 7 basic
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Expressing hydronium concentrations in scientific notation isn’t very convenient. The pH scale was developed to make the expression of H 3 O + concentration more convenient. [H 3 O + ] is the concentration in mol/L pH = -log[H 3 O + ]
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Back of book
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Net Ionic Equations The chemical reaction equation can be written with just the chemicals which will react and form precipitates.
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Applications of Stoichiometry To determine the overall experiment the percent yield is used. This lets us know about the experimental uncertainties – Measurements, purity, washing, estimations
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Summary
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Limiting Reactions There is only a certain amount of one of the reacting chemicals and when all of it is used up the reaction stops – this is the limiting reagent The other reactant is more abundant and is called the excess reagent
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Limiting and Excess Reagent Having a reactant with excess means that more of the substance is present then required for the reaction. We our purposes we will use the value of 10 % for the excess amount required to make the reaction occur. Sample problem 8.1 pg 320
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Interpreting Titration pH Curves Pg. 334
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