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1 Chapter 5 Chemical Reactions and Quantities 5.6 Molar Mass
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2 The molar mass is the mass of one mole of an element or compound. is the atomic mass expressed in grams. Copyright © 2005 by Pearson Education, Inc. Publishing as Benjamin Cummings
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3 Molar Mass from Periodic Table Molar mass is the atomic mass expressed in grams. 1 mole Ag 1 mole C 1 mole S = 107.9 g = 12.01 g = 32.07 g
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4 Give the molar mass for each (to the tenths decimal place). A. 1 mole K atoms =________ B. 1 mol Sn atoms =________ Learning Check
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5 Give the molar mass for each (to the tenths decimal place). A. 1 mole K atoms =39.1 g B.1 mole Sn atoms =118.7 g Solution
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6 Molar Mass of a Compound The molar mass of a compound is the sum of the molar masses of the elements in the formula. Example: Calculate the molar mass of CaCl 2. ElementNumber of Moles Atomic MassTotal Mass Ca140.1 g/mole 40.1 g Cl235.5 g/mole 71.0 g CaCl 2 111.1 g
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7 Molar Mass of K 3 PO 4 Calculate the molar mass of K 3 PO 4. ElementNumber of Moles Atomic MassTotal Mass in K 3 PO 4 K339.1 g/mole 117.3 g P131.0 g/mole 31.0 g O416.0 g/mole 64.0 g K 3 PO 4 212.3 g
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8 Some One-mole Quantities 32.1 g 55.9 g 58.5 g 294.2 g 342.2 g One-Mole Quantities
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9 What is the molar mass of each of the following? A. K 2 O B. Al(OH) 3 Learning Check
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10 A. K 2 O 94.2 g/mole 2 mole K (39.1 g/mole) + 1 mole O (16.0 g/mole) 78.2 g + 16.0 g = 94.2 g B. Al(OH) 3 78.0 g/mole 1 mole Al (27.0 g/mole) + 3 mol O (16.0 g/mole) + 3 mol H (1.01 g/mole) 27.0 g + 48.0 g + 3.03 g = 78.0 g Solution
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11 Prozac, C 17 H 18 F 3 NO, is an antidepressant that inhibits the uptake of serotonin by the brain. What is the molar mass of Prozac? 1) 40.1 g/mole 2) 262 g/mole 3) 309 g/mole Learning Check
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12 Prozac, C 17 H 18 F 3 NO, is an antidepressant that inhibits the uptake of serotonin by the brain. What is the molar mass of Prozac? 3) 309 g/mole 17 C (12.0) + 18 H (1.01) + 3 F (19.0) + 1 N (14.0) + 1 O (16.0) = 204 + 18.2 + 57.0 + 14.0 + 16.0 = 309 g/mole Solution
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13 Molar mass conversion factors are written from molar mass. relate grams and moles of an element or compound. Example: Write molar mass factors for methane, CH 4, used in gas stoves and gas heaters. Molar mass: 1 mol CH 4 = 16.0 g Conversion factors: 16.0 g CH 4 and 1 mole CH 4 1 mole CH 4 16.0 g CH 4 Molar Mass Factors
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14 Acetic acid C 2 H 4 O 2 gives the sour taste to vinegar. Write two molar mass conversion factors for acetic acid. Learning Check
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15 Acetic acid C 2 H 4 O 2 gives the sour taste to vinegar. Write two molar mass factors for acetic acid. Calculate molar mass: 24.0 + 4.04 + 32.0 = 60.0 g/mole 1 mole of acetic acid = 60.0 g acetic acid Molar mass factors 1 mole acetic acid and 60.0 g acetic acid 60.0 g acetic acid 1 mole acetic acid Solution
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16 Molar mass factors are used to convert between the grams of a substance and the number of moles. Calculations Using Molar Mass Grams Molar mass factor Moles
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17 Aluminum is often used to build lightweight bicycle frames. How many grams of Al are in 3.00 mole Al? Molar mass equality: 1 mole Al = 27.0 g Al Setup with molar mass as a factor: 3.00 mole Al x 27.0 g Al = 81.0 g Al 1 mole Al molar mass factor for Al Moles to Grams
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18 Learning Check Allyl sulfide C 6 H 10 S is a compound that has the odor of garlic. How many moles of C 6 H 10 S are in 225 g?
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19 Calculate the molar mass of C 6 H 10 S. (6 x 12.0) + (10 x 1.01) + (1 x 32.1) = 114.2 g/mole Set up the calculation using a mole factor. 225 g C 6 H 10 S x 1 mole C 6 H 10 S 114.2 g C 6 H 10 S molar mass factor (inverted) = 1.97 mole C 6 H 10 S Solution
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20 Grams, Moles, and Particles A molar mass factor and Avogadro’s number convert grams to particles. molar mass Avogadro’s number g mole particles particles to grams. Avogadro’s molar mass number particles mole g
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21 Learning Check How many H 2 O molecules are in 24.0 g H 2 O? 1) 4.52 x 10 23 2) 1.44 x 10 25 3) 8.03 x 10 23
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22 Solution How many H 2 O molecules are in 24.0 g H 2 O? 3) 8.02 x 10 23 24.0 g H 2 O x 1 mole H 2 O x 6.02 x 10 23 H 2 O molecules 18.0 g H 2 O 1 mole H 2 O = 8.03 x 10 23 H 2 O molecules
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23 Learning Check If the odor of C 6 H 10 S can be detected from 2 x 10 -13 g in one liter of air, how many molecules of C 6 H 10 S are present?
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24 Solution If the odor of C 6 H 10 S can be detected from 2 x 10 -13 g in one liter of air, how many molecules of C 6 H 10 S are present? 2 x 10 -13 g x 1 mole x 6.02 x 10 23 molecules 114.2 g 1 mole = 1 x 10 9 molecules C 6 H 10 S
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