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A. Definitions 1. Chemistry 2. Matter CHEMISTRY I. Introduction
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Anything that occupies space and has mass.
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3. Energy
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a. Potential
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b. Kinetic
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c. Forms Chemical Electrical Mechanical Radiant
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4. Elements
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A. Particles II. Atomic Chemistry
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Figure 2.1
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B. Structure
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Figure 2.2
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C. Atomic & Mass Number
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D. Isotopes & Radioisotopes
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Figure 2.3
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Isotope = atom with more neutrons Radioisotopes neutrons measurably decay giving off radiation (alpha and beta particles, plus gamma rays) Decay Rate = half life
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E. Electronegativity & Valence
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Electronegativity => degree of attraction for electrons Valence => number of electrons in the outermost shell Figure 2.5
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A. Definition 1. Definition 2. Types III. Molecular Chemistry B. Chemical Bonds a. Electron Sharing
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i. Ionic bonds giving and taking of electrons Figure 2.6a Figure 2.6b
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ii. Polar Covalent bonds unequal sharing Figure 2.6
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iii. Non-polar covalent bonds equal sharing
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iii. Non-polar covalent bonds equal sharing
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b. Hydrogen Sharing
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Hydrogen bonds sharing a hydrogen atom between molecules Figure 2.10a
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A. Definition 1. Synthesis, Dehydration, or Anabolic 2. 2. Decomposition, Decomposition, Hydrolytic, Hydrolytic, or or Catabolic IV. Chemical Reactions B. Types 3. Exchange
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A (OH) + B (H) AB + H2OH2O CD + H 2 O C (OH) + D (H) AB + CD AC + BD
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Figure 2.11
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C. Factors Affecting Rates
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A. Water 1. Properties V. Inorganic Molecules
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States of Water
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Polar Figure 2.7
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H-Bonding Potential Figure 2.8
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Density
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Cohesive Forces
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2. Uses
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Solvent Figure 2.12
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Temperature Stabilizer or Heat of Vaporization
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B. Salt (Electrolytes) 1. Properties
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2. Uses
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C. Acids, Bases, pH, & Buffers 1. Definitions & Uses
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An acid increases the hydrogen ion concentration H 2 CO 3 HCO 3 - + H + (Carbonic) H 2 SO 4 H + + H + + SO 4 2- (Sulfuric) HCl H + + Cl - (Hydrochloric)
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A base decreases the hydrogen ion concentration HCl + NaOH NaCl + H 2 O (Sodium Hydroxide)
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pH Scale measures the hydrogen ion concentration Figure 2.13
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A buffer regulates the pH of a solution HCO 3 - + H + H 2 CO 3 HPO 4 -2 + H + H 2 PO 4 - NH 3 + H + NH 4 +
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A. Why Carbon? VI. Organic Molecules
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B. Carbohydrate 1. Atoms 2. Arrangement of Atoms
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Carbon, Hydrogen, and Oxygen (CH 2 O) Figure 2.12
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Isomers
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3. Types
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a. Monosaccharide = glucose, fructose, galactose, or ribose
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b. Disaccharide = two simple sugars together Glucose + Fructose Sucrose + H2OH2O Glucose + Galactose Lactose + H2OH2O
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c. Polysaccharides = many simple sugars together Chitin found in insect exoskeletons
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4. Biological Uses
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C. Lipids 1. Atoms 2. Arrangement of Atoms 3. Types
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a. Neutral Fats = glycerol with fatty acid chains (monoglyceride, diglyceride, or triglyceride) Saturated vs. Unsaturated
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b. Phospholipids = glycerol, two fatty acids, and a polar phosphate group.
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c. Steroids = carbon ringed with attachments giving different properties Cholesterol Estrogen Testosterone
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4. Biological Uses
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D. Protein 1. Atoms 2. Arrangement of Atoms
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Figure 2.15a
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3. Types
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Depends on the amino acid sequence conformation vs. denaturation
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4. Biological Uses
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Proteins vary in function from being Contractile, Defensive, Enzymatic, Signal, Storage, Structural, to Transporter. Everything about a protein’s function is reliant on its conformation, that is dictated by its amino acid sequence.
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E. Nucleic Acids 1. Atoms 2. Arrangement of Atoms
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Nucleotides are one of five types adenine, thymine, cytosine, and guanine in DNA, and substitute uracil for thymine in RNA. Figure 2.17
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3. Types
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DNA vs. RNA Strands double single Bases A,T,G, & C A, U, G, & C Sugars deoxyribose ribose Size huge portion of DNA Location nucleus nucleus & cytoplasm Types one three (mRNA, tRNA, & rRNA)
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4. Biological Uses
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F. Adenosine Triphosphate 1. Atoms 2. Arrangement of Atoms 3. Types
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ATP, TTP, GTP, CTP, & UTP Figure 2.18
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4. Biological Uses
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A. Structure VI. Enzymes
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B. Function
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1. How enzymes work Figure 2.20
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1. & Why? Figure 2.21
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C. Regulation
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1. Competition
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2. Feedback Inhibition
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3. Allosteric Control
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