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Emission Spectra and Flame Tests
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The Big Questions What is light? How is light emitted? What do electrons have to do with light? What are emission spectra? How do flame tests help identify metals?
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The Electromagnetic Spectrum All light is part of the EM spectrum. Most is invisible: gamma, X-rays, UV, IR, microwaves, radio waves Visible light: wavelength (w.l.) from 400 to 700 nm.
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The EM Spectrum
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EM Radiation Light is a carrier or quantum of energy. It is emitted by vibrating charges (like electrons). Light can transfer energy to electrons. Heat can also excite electrons.
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Energy of Electrons Ground State The lowest possible energy of the electron Excited State Electron that absorbs energy and has moved to a higher energy level
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Adding Energy Electrons move from a lower energy level to a higher energy level This occurs when the electron absorbs light
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Light and Electrons Ground state (G.S.) electron Excited state (E.S.) electron Light
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Losing Energy Electrons give off energy (light) as they move from a higher energy level to a lower energy level Energy of light corresponds to the energy gap between ground state and excite state Sometime the light is visible
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Light and Electrons Ground state (G.S.) electron Excited state (E.S.) electron
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Lyman Series Lines at the ultraviolet end of the hydrogen spectrum Electrons move from a higher energy level to n=1
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Balmer Series Lines in the visible spectrum Electrons move from a higher energy level to n=2
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Paschen Series Lines at the infrared end of the hydrogen spectrum Electrons move from a higher energy level to n=3
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Emission Spectrum Emission spectrum – colors of light given off by an element when it is excited (usu. by heat). Every element has an unique emission spectrum.
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Emission Spectra Hydrogen Helium Carbon
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Flame Tests Flame test – used to ID some metals in compounds. Each metal gives a flame a characteristic color. Can identify metals based on flame colors.
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