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Topic 10 Correlates to Topic 10 in review book, pages 174-188
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Acids = substances that react with a base; often has a low pH May be strong or weak Actual definition depends upon the type of acid/base Bases = substances reacting with an acid; often has a high pH May be strong or weak 3 major types of acids and bases here
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Acids: o Taste sour o Conduct current in solution o React with bases to form water and salt o React with some metals to make H2(g) o Low pH Bases: o Taste bitter o Slippery/soapy feeling o Conduct current in solution o React with acids to form salt water o Have low pOH or high pH
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1. Arrhenius 2. Bronsted-Lowry
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Acid = substances that release hydrogen ions in aqueous solutions proton donors Ex.] HCl H + + Cl - Base = substances that release hydroxide ions in aqueous solutions Hydroxide donors Ex.] NaOH Na + = OH -
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Acid = any substance that can donate hydrogen ions in solution o Proton donors Ex.] HCl H + + Cl - Base = any substance that can accept hydrogen ions in solution Proton acceptors Ex.] NH3 + H + NH4 +
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Acid = any species that can accept an electron pair from another species in solution Ex.] H + + NH3 Base = any species that can donate an electron pair to another species in solution NH4 +
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STRONG acids/bases will completely dissociate [ionize] in solution Ex.] HCl, HNO 3, H 2 SO 4, NaOH, KOH, etc. WEAK acids/bases produce very few ions per molecule in solution Ex.] vinegar, H 3 PO 4, formic acid, citric acid, etc.
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Acid/Base Conjugates = species that are formed in solution as a result of the dissociation of an acid or base Ex.] HCl + NaOH Na + + Cl - + HOH o Cl - is the conjugate base o Na + is the conjugate acid
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Titration = method used to determine the pH of an unknown solution Process to find the concentration of an unknown acid/base by neutralizing it with a base/acid of known concentration An indicator signals the equivalence point and tells that the neutralization is complete
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Uses burets, a standard solution of known pH, an indicator, and a fixed volume of a solution with an unknown pH Titration Formula: M a V a = M b V b http://www.youtube.com/watch?v=u9nOIZDdvRw http://www.youtube.com/watch?v=u9nOIZDdvRw
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Acid + Base = Salt + water Acids and bases neutralize each other H + + OH - H 2 O
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pH = the scale, 0-14, that defines the acidity or basicity of a solution Based on the concentration of hydrogen ions 0-6 = acid 7= neutral 8-14 = base
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pOH = the measure of the concentration of OH- ions in solution Opposite of pH Scale 0-14 0-6 = strong base 7= neutral 8-14 = acidic
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pH + pOH = 14 always! pH = -log[H + ] pOH = -log[OH - ]
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Ex. 1] What is the pH of a solution containing 9.15 x 10 -6 M H + ? Ex. 2] What is the pH of a solution containing [OH - ] = 8.11 x 10 -5 M in 350.mL of solution?
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Indicators = compounds that change color when the pH changes o Color changes indicate the pH of the solution! o Use several indicators to pinpoint the final pH!
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Find the pH using the indicator and its color in the solution… Tutorial on indicators: http://www.kentchemis try.com/links/AcidsB ases/Indicators.htm
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