1. Analytical System Integration 2014 National Sales Meeting
CGA: Continuous Gas Analyzers
Analyzer or Application – The Question
Bruce Herman - ABB Process Analytics
Applied Controls
Analytical System Integration
2014 National Sales Meeting

2. © Copyright 2014 ABB
All rights reserved
“The information contained in this document is to be used only for the purpose intended. Any unauthorized use, reproduction, distribution or disclosure to third parties without permission is strictly forbidden. ABB reserves all of its intellectual property rights in and to the information and the document.”

3. ANALYZERS and APPLICATIONS
name where ABB sells CGA analyzers
identify measuring points in the major applications
select the right analyzer modules for applications

4. Agenda - Focus Points PRESENTATION FOCUS CGA – the product
The Frankfurt Connection
PRESENTATION FOCUS
Product overview
CGA: AO2000
CGA – the product
Where do you find CGA
Emissions
Process
APPLICATIONS
POI
(Points of Interest)
DIALOG

5. ADVANCE OPTIMA 2000 Advance Optima – Reliable – Economic – Powerful
Available for >15 years
Powerful controller logic
Class 1, Groups A,B,C,D, Div 2
Engineered

6. Continuous Gas Analyzers
The Benefits of an Integrated Analyzer Concept CO
CO2
NOx O2
Sample Handling

7. The most important area of applications for continuous gas analysis
The most important area of applications for continuous gas analysis. Combustion processes can be found in many different industrial areas,

8. COMBUSTION PROCESSES the generation of heat and electricity,
Process steam production,
Municipal and hazardous waste incineration,
Surface treatment for example in annealing processes,
Melting processes as used in metal or glass production,
Roasting process for example iron ore roasting, sintering,
Steel production and
Cement production, … to name only the most important.

9. CO2, H2O, N2 expected
CO, HC, excess O2 incomplete combusion
SO2, NOx Sulfur in fuel, N2
HCl, HF (Waste Incin)
Hg, Particulates

11. Combustion efficiency
Ideal combustion needs the right amount of oxygen.
The oxygen value can be measured with a paramagnetic oxygen analyzer

12. Efficiency of DeNOx process
Nitrogen oxide and nitrogen dioxide are a major cause for environmental damage.
These components are removed by injection of ammonia.
The injection of ammonia is regulated via the NO/NO2 concentration in the exhaust gas. The efficiency of this process is controlled by monitoring the outlet for excess ammonia. Analyzers used are infrared photometer
Infrared for NO
or alternatively ultra-violet photomete for NO and NO2, and laser analyzer for NH3 measurement.

13. Electrostatic precipitator
The typical measuring component is carbon monoxide.
Since CO is a flammable gas this measurement represents a safety measurement to avoid explosions.
Infrared photometer.

14. Efficiency of the DeSOx process (desulfurization)
The efficiency of the flue gas desulfurization is monitored
by measurement of SO2 with Infrared.
Alternately UV

16. The analyzer modules module name type typical Uras 26 NDIR photometer
CO, CO2
Limas11 IR
IR photometer
CO,CO2, HCl
Limas11 UV
Limas 23 UV
UV photometer
NO, NOx
Magnos 206
Paramagnetic, dumbbell O2
Magnos27
Heavy duty
Caldos 27
Fast silicon sensor, TC H2
Caldos 25
Glass coated TC
Chlorine NH3, SO2
FIDAS24
Flame ionization
Fidas24 NMHC
Non-meth HC, VOC
ZO23
Zirconium dioxide
O2 traces
LS4000
Laser in-situ
O2, CO, NH3
Oxygen cell
chemical

17. ADVANCE OPTIMA 2000
ABB

18. Infrared Analyzer Module ABB Uras 26
Analyzer Modules
Infrared Analyzer Module ABB Uras 26 CO
CO2
SO2 NO
CH4 ….

19. Uras26 Fulfils all the requirements for a lot of applications
High Stability of zero and span point <1% drift per week
High Sensitivity and smallest measuring ranges ppm CO2
High Selectivity smallest cross sensitivities optimized for the main applications
Smallest detection limits < 20 ppb in a range of 0…5 ppm CO2
Suppressed range like 98…100 Vol% N2O
High repeatability < 0,5% of the range
Gas filled detector
Membrane condensator
Sample cell

20. Infrared, Principle CO
SO2 N2 N2 CO
SO2 N2 N2 N2 N2
CH4 NO
ABB Uras 14 with 4 measured components and calibration cells N2 N2
CH4 p NO

21. Photometer Analyzer Modules ABB Limas 11-UV/IRNO
SO2
NO2
NOx = NO + NO2

22. Limas 11-UV UV Simple adaption to the measuring task
Various Measuring components: NO, NO2, SO2, H2S, CS2, COS, Cl2 and NH3
Low measuring ranges: 10 ppm NO,
High Selectivity by best choice of - Interference and Gas Filter - Internal cross-sensitivity correction
High Stability due to electrodeless source & unique 4-Beam Method
Compact & economical solution for flammable, corrosive & toxic process gases
Calibration without test gas bottles UV
Meßkomponenten for die Verfahrenstechnik
Niedrige Meßbereiche u.a. NO for Emissionmessungen
Simple adaption to the measuring task

23. Limas 11 - Schematic Drawing
Source
FW1 CU IF GF
FW2 M GF M
CL3 BS D2 MC
IM2
IM1
CL2
CL1
IR2 t D1
IR1 t
IR - Source
M Motor
FW1 Filter wheel 1
FW2 Filter wheel 2
BS Beam splitter
MC Measuring cuvette
CL1,2,3 Collimator lenses
D1, Detectors
CU Calibration unit
IF Interference filters
GF Gas filters

24. Oxygen Analyzer Modules Magnos 206/27

25. Magnos – and Oxygen Technology
Measurement in many applications
Very few interferences
Paramagnetic analyzer
Measuring with a dumbbell
Magnos27
Preferred for rugged applications
No moving parts
Measuring using thermal character
Electrochemical
Simple and economical
Laser Diode
In Situ
NOT Paramagnetic

26. Magnos 206
Fast, Reliable Measurement Magneto-Mechanical Principle

27. Magnos27 Technology Paramagnetism of oxygen
Two chamber system (measurement and reference)
Measurement chamber is located in a magnetic field
Temperature dependent resistors
Measurement effect: Increased circulatory flow proportional to oxygen concentration measured through thermal conductivity.

28. Magnos 27 Robust Measuring Cell Thermomagnetic Principle
Temperature dependent
resistors
( Pt/Glass ... ca. 180 °C )
Bypass
60 °C
Natural Gas
Oil
Coal

29. Oxygen Sensor Extended Range of Application, Suited for Stack Gas Monitoring
PTFE Membrane
Cathode ( Au )
Anode ( Pb ) - +
Sample gas
Electrolyte ( acidic )

30. LS4000 (TDL) Overview In situ tunable diode laser analyzer
Measurement of oxygen (from 0-1 to 0-100Vol%)
Stand-alone operation
Compact & flameproof housing approved for use in hazardous areas (ATEX/IECEx/FM/CSA) (Class I, Div 1)
Dynamic correction of changing process conditions

31. LS4000 Product overview

32. Caldos 25 Highly corrosion resistant glass coated resistors

33. Caldos 25 Independent of Ambient Pressure Sophisticated Measuring Cell
Reference side
Measuring side
Bypass
Glass-
coated
Glass
60 °C

34. Caldos 17 Fast Measurement

35. FID Analyzer Module FIDAS24
Analyzer Modules
FID Analyzer Module FIDAS24

36. Fidas24 Key Features at a Glance
New FID analyzer for Advance Optima and EasyLine series
Continuous hydrocarbon and non-methane hydrocarbon analysis
Large operating range: from low ppm to high vol%
Easy to operate

37. AO2000 Series Analyzers

38. AO2000 Series Analyzers

39. AO2000 Series Analyzers

41. APPLICATIONS Power Generation CEMENT KILNS boilers furnaces heaters
CEMS – 70%
Power Generation
CEMENT KILNS
boilers
furnaces
heaters
incinerators
(if it burns…. )
PROCESS – 30%
Cement Kilns
CO2 in hydrocarbons
CO in hydrogen
H2 in Cl2
H2 in Hydrocarbons (nitrogen header..)
O2 deficiency
FID, incinerators, Hydrocarbon in water
Special Emphasis
NO and NO2 measurements for CEMS (LIMAS23 and LIMAS11)
Landfill gas measurements
CH4, CO2, O2
GREENHOUSE GAS
CSA has a regulation
Nitric Acid Plants
NO/NO2 ratio issues
Partner Partnering

42. Integrated Remote Control Full Access to Gas Analyzers Functionality
You can start a remote session with the targeted analyzer immediately after right mouse click on the AO-icon

43. Thank You For Your Time www.analyzer-systems.com