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Model Compounds for the Photochemical Study. Mechanism of Coupling Reaction Primary factors controlling the overall reaction need to be understood. Possible.

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Presentation on theme: "Model Compounds for the Photochemical Study. Mechanism of Coupling Reaction Primary factors controlling the overall reaction need to be understood. Possible."— Presentation transcript:

1 Model Compounds for the Photochemical Study

2 Mechanism of Coupling Reaction Primary factors controlling the overall reaction need to be understood. Possible approaches include, -Electrochemical oxidation/spectroelectrochemistry -Radiolysis to identify reaction kunetics and mechanism -Medium effects on the reaction kinetics -Identify propagating or quenching reactions

3 –Substituent groups alter the dye color –pH can bring about significant changes in the coloration – oleic acid serves as both buffering agent & surfactant – high surfactant concentration is known to minimize the amount of water which in turn favors the local peroxide concentration Medium Effects red blue red pKa 10.4pKa 3.4

4 Reactive Dyes Or Reactive Black 5 Sonolytic Degradation Vinodgopal & Kamat, Water Research, 1998, 32,3646-3650 Background information on dyeing of wool and other fibers with reactive dyes may be useful in considering alternate systems


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