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Published byEthel Morris Modified over 9 years ago
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Model Compounds for the Photochemical Study
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Mechanism of Coupling Reaction Primary factors controlling the overall reaction need to be understood. Possible approaches include, -Electrochemical oxidation/spectroelectrochemistry -Radiolysis to identify reaction kunetics and mechanism -Medium effects on the reaction kinetics -Identify propagating or quenching reactions
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–Substituent groups alter the dye color –pH can bring about significant changes in the coloration – oleic acid serves as both buffering agent & surfactant – high surfactant concentration is known to minimize the amount of water which in turn favors the local peroxide concentration Medium Effects red blue red pKa 10.4pKa 3.4
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Reactive Dyes Or Reactive Black 5 Sonolytic Degradation Vinodgopal & Kamat, Water Research, 1998, 32,3646-3650 Background information on dyeing of wool and other fibers with reactive dyes may be useful in considering alternate systems
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