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Published byHoratio Morris Modified over 9 years ago
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If opposite charges attract, why are the negative electrons not attracted to the positive nucleus?
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Electrons are always moving. Electrons have inertia in motion = momentum.
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If electrons are always moving and they weigh very, very little, why don’t they get thrown away out of the atom?
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Because of the electromagnetic force!
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Forces inside the atom This force of attraction binds the electrons to the atom. The electromagnetic force becomes stronger as the distance between charges becomes smaller.
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If opposite charges attract, how do the protons get attracted with the neutrons?
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Because of the strong nuclear force!
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Forces inside the atom Protons and neutrons in the nuclei of atoms are held together by the strong force.
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If the atomic mass/weight is just the sum of the protons and neutrons, why are there decimal values for the atomic weight written on the periodic table?
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Atomic Weight is an Average! It is the weighted average of the individual atomic weights, or mass numbers, of the isotopes.
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Example Chlorine = 35.48 (atomic weight) Isotopes of Chlorine Chlorine-35 = 76% abundance Chlorine-37 = 24% abundance Σ(mass number x %abundance)
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Example The mass of Isotope 1 is 6.015 amu and its abundance is 7.5% The mass of Isotope 2 is 7.016 amu with a 92.5% abundance. What is the average atomic mass? What is the element?
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The Periodic Table
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Johann Dobereiner (1829) Triads!
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The elements in a triad had similar chemical properties and orderly physical properties. Calcium, Strontium, Barium Chlorine, Bromine, Iodine
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John Newlands (1863) Octaves!
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After arranging the elements in order of increasing atomic mass, certain properties repeated every 8th element.
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Lothar Meyer (1867) Increasing atomic mass!
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Dmitri Mendeleev (1869) “Father of the Periodic Table”
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Both scientists left vacant spaces where unknown elements should fit.
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Periodic Table, I am your Father. Dmitri Mendeleev (1869)
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The weight must be wrong. Reclassify! Dmitri Mendeleev (1869)
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Increasing atomic NUMBER! Henry Moseley (1913)
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Through his work with X-rays, he determined the actual nuclear charge (atomic number) of the elements. He rearranged the elements in order of increasing atomic number.
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Actinide and Lanthanide Series! Glenn Seaborg (1944)
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He reconfigured the periodic table by placing the actinide series below the lanthanide series
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Periodic Table Geography
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George M. McKelvy, Ph.D.33 The Modern Periodic Table Columns of elements are called groups.
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George M. McKelvy, Ph.D.34 The Modern Periodic Table Rows of elements are called periods.
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The Alkali Metals 1 valence electron Highly reactive with water Form ionic compounds Do not occur in nature as pure elements (always in compounds)
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Alkali-Earth Metals Have 2 valence electrons Reactive, but less reactive than alkali metals Are ductile, malleable and have a silvery luster
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Transition metals… and inner transition metals Are less reactive than groups 1 and 2. Tend not to react in water. Are malleable and ductile, but still harder than group 1 & 2. Tend to be solids at room temperature. Have variable chemical properties Are good conductors of electricity and heat. Inner transition metals tend to be radioactive
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Nonmetals Poor conductors of heat and electricity Often are found as gases or liquids, sometimes solids.
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Halogens Are nonmetals highly reactive with metals- most reactive is flourine, lease reactive is astatine Mostly exist as gases or liquids (except At -solid) Have 7 valence electrons
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Noble gases At room temperature, exist as gases. Are completely unreactive Have full s and p orbitals Are odorless, colorless, nonflammable
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Metalloids Tend to be solids Have properties similar to both metals and nonmetals Tend to be semiconductors (which means they are useful for technological uses)
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Periodic Law When elements are arranged in order of increasing atomic number, there is a periodic pattern in their physical and chemical properties.
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Metals, metalloids (semi-metals) and non- metals
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Properties of Metals Good conductors of heat and electricity: lots of mobile electrons to move energy and charge around Have luster (shiny) Are ductile (stretchable) and malleable (bendable) Solids at room temp. except for Hg
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Properties of Metalloids Have properties of both metals and non-metals Some of them are semiconductors (like silicon) which behave sometimes as conductors and sometimes as insulators Solids at room temperature
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Properties of Non-Metals Poor conductors of heat and electricity Can be solids, liquids or gases (contrary to popular belief not all non-metals are gases!) Are not ductile, malleable
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Periodic Trends - Reactivity – how likely or vigorously an atom is to react with other substances – Usually determined by how easily electrons can be removed and how badly they want to take other atom’s electrons since it is the transfer/interaction of electrons that is the basis of chemical reactions
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Periodic Trends - Reactivity Metals – Period: DECREASES from left to right – Group: INCREASES down a group WHY? The farther left and down the periodic table, the easier it is for elections to be given or taken away, resulting in a higher reactivity
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Periodic Trends - Reactivity Non-metals – Period: INCREASES from left to right – Group: DECREASES down a group WHY? The farther right and up the periodic table, the higher the electronegativity, resulting in a more vigorous exchange of electrons
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