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Structure and Bonding Molecular Orbital Theory Hybridization Isomerization Dipoles and Polarity
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Orbitals are Probabilities Motion of Electrons Described as Wave Functions
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2s Orbital Has a Node
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Bonding in H 2 Sigma ( Bond
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Wave Depiction of H 2 Waves reinforce
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Molecular Orbitals Mathematical Combination of Atomic Orbitals
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Antibonding Molecular Orbital Destructive Overlap Creates Node
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and * of H 2 Each Wave Function Corresponds to a Different Energy State for an Electron
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Energy Released When Bond Forms
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The p Orbital
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p x, p y, p z
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Ground State Electron Configurations
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Electron Configuration of Carbon
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Lewis Dot Structure of Methane
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Tetrahderal Geometry
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Methane Representations
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In Ground State 2 bonding sites, 1 lone pair
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sp 3 Hybridization 4 Regions of electron Density link link
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Hybridization of 1 s and 3 p Orbitals – sp 3
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sp 3 is Tetrahedral Geometry Methane
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Ammonia Tetrahedral Geometry Pyramidal Shape
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All Have the Same Geometry All Have 4 Regions of Electron Density
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Orbital Depiction of Ethane, C 2 H 6, the bond
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Bonding Characteristics of Period 2 Elements
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A Saturated Hydrocarbon
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sp 2 Hybridization 3 Regions of Electron Density
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Hybridization of 1 s and 2 p Orbitals – sp 2
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An sp 2 Hybridized Atom
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Ethylene CH 2 =CH 2
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Views of Ethylene, C 2 H 4
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Ethylene
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Formaldehyde
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sp Hybridization 2 Regions of Electron Density
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The sp Orbital
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Acetylene, C 2 H 2, 1 bond 2 perpendicular bonds
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Pauling Electronegativity Scale
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Electrostatic Potential Map Cholormethane
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Opposite polarity in CH 3 Li
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Methanol
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Dipole Moment ( ) is sum of the Bond Moments
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Nonpolar Compounds Bond Moments Cancel Out
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Dipole Moment reflects Both Resonance Structures
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NCl 3 and BCl 3
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Dipole Moments
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Dipole-Dipole Interactions
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London Dispersion Forces
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The Effect of Branching on Boiling Point
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Polar Solute in H 2 O
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Polar Solute in Nonpolar Solvent
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Nonpolar Solute in Nonpolar Solvent
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Hydrogen Bonding
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