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Water, Part 2 Wastewater Treatment Primary Chapter: 11 Supplemental Chapters: 8, 9 1
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Activity What’s the problem with direct discharge of untreated wastewater? Write your ideas. Share with a partner. Share with the class. 2
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Treatment Processes Treatment process = f(amount, type/source) Discharge limits = f(type/source, discharge location, time of year) 3
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CENTRALIZED TREATMENT 4
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Types of Wastewater (Section 11.1.1) From where does it all come? 5
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Transport of WW 6
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Characteristics of WW (Section 11.1.2) 7
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Activity Why is it important to obtain local data on wastewater composition and flow rates rather than using typical data when designing a new or an expansion to a treatment plant? Write your ideas. Share with a partner. Share with the class. 8
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Regulations (Sections 9.3.2 and 9.3.3) What’s the primary law for WWT? 9
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Activity Who must obtain an NPDES permit? A. Manufacturers B. Point source dischargers C. Farmers D. Septic tank owners E. Municipalities 10
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Typical Municipal WWTP 11
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Raw Sewage Bar Rack Grit Chamber Equalization Basin Pump Primary Clarifier Biological Treatment Secondary Clarifier Disinfection Receiving Body Advanced or Tertiary Treatment Preliminary Treatment Primary Treatment Secondary Treatment Solids Handling Degrees of Treatment - Example 12
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BOD Solids Influent – How much is removed? 13
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After Primary Treatment 14
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After Secondary Treatment 15
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Preliminary Treatment (Section 11.2.1) Screens Comminutors (Grinders) Bar Racks Grit Chamber 16
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Primary Treatment (Section 11.2.2) 17
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Secondary Treatment (Section 11.3) 18
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OXYGEN DEMAND Section 9.1.2 19
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Oxygen Demand Amount of oxygen required to oxidize a waste Methods Theoretical oxygen demand (ThOD) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) 20
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Theoretical Oxygen Demand Total ThOD = C-ThOD + N-ThOD C-ThOD = stoichiometric amount of O 2 required to convert an organic substance to CO 2, H 2 O, and NH 3 N-ThOD = stoichiometric amount of O 2 required to convert NH 3 and organic N to NO 3 - 21
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Example 1 What is the total ThOD to oxidize completely 25 mg/L of ethanol (CH 3 CH 2 OH)? CH 3 CH 2 OH + a O 2 b CO 2 + c H 2 O 22
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Determine Volume of O 2 or Air 23
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Example 2 What is the ThOD to oxidize completely 25 mg/L of serine (CH 2 OHCHNH 2 COOH)? CH 2 OHCHNH 2 COOH + a O 2 b CO 2 + c H 2 O + d NH 3 NH 3 + a O 2 b HNO 3 + c H 2 O 24
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Biochemical Oxygen Demand (BOD) 25
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Lab: Unseeded BOD BOD t = BOD at t days (mg/L) DO i = initial dissolved oxygen (mg/L) DO f = final dissolved oxygen (mg/L) V s = sample volume (mL) V b = bottle volume (mL) = 300 mL DF = dilution factor = V b /V s 26
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Lab: Seeded BOD B i = initial DO of blank (mg/L) B f = final DO of blank (mg/L) 27
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In-Class Activity 10 mL of a wastewater sample are placed in a 300-mL BOD bottle with unseeded nutrient broth. The initial DO of the sample is 8.5 mg/L. The DO is 3 mg/L after 5 days. What is the 5-day BOD? A 17 o C sample is initially saturated with oxygen. Saturated seeded dilution water is used to obtain a 1:25 dilution. The final DO of the seeded dilution water is 8.2 mg/L while the final DO of the diluted sample is 2.8 mg/L. What is the 5-day BOD? 28
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In-Class Activity Bottle NumberType 1 DO (mg/L) 10B8.91 14B8.89 18S7.85 22S8.15 28S8.52 1 B = blank (seeded dilution water), S = sample with seeded dilution water You received the results of a BOD test of the influent to a municipal WWTP run with 300-mL bottles. The initial DOs of the samples and seeded dilution water were at saturation (9.07 mg/L). All samples were run at a dilution factor of 40:1. The 5-day DOs are shown in the table below. The client is on the phone with your boss wanting to know why he hasn’t gotten a report yet. Justify why you threw out this data and made the lab redo the test. 29
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Rate of BOD Removal Relate BOD exerted (BOD t or L t ) to total, or ultimate, BOD (BOD u or L) Assume that the BOD reduction rate (dC/dt) is proportional to the BOD remaining (C): 30
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Rate of BOD Removal cont. Integration yields: y = BOD exerted in t days = BOD t L = ultimate BOD = BOD u k 1 = BOD degradation rate constant = deoxygenation constant 31
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Ultimate BOD 32
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In-Class Activity continued 10 mL of a wastewater sample are placed in a 300-mL BOD bottle. The initial DO of the sample is 8.5 mg/L. The DO is 3 mg/L after 5 days. What is the 5-day BOD? 165 mg/L What is the 3-day BOD if the reaction rate constant is 0.23/d? 33
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Chemical Oxygen Demand (COD) 34
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Secondary Treatment (Section 11.3) 35
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Activated Sludge: Aeration Basin (Sections 11.3.2 - 11.3.4) 36
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Aeration Basin Design Kinetics Mean cell residence time & hydraulic detention time 37
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Kinetics: Logistic Growth (d - 1 ) S (mg/L) max max / 2 KsKs 38
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Aeration Basin Design Mean cell residence time & hydraulic detention time 39
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MCRT from a Reactor without Recycle V, S, X Q, S o, X o Q, S, X 40
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Wasting from Recycle Line Q, S o, X o V, S, X Q e = Q-Q w, S, X c VcVc Q r, S, X r Q w, S, X r 41
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Example A conventional WWTP receives 2 MGD with an average BOD of 165 mg/L to the aeration basin. The aeration basin is 100,000 ft 3. The MLSS is 2,800 mg/L and the effluent SS is 25 mg/L. The WAS is 38,000 gpd from the recycle line. The SS of the recycle flow is 9,000 mg/L. What is the mean cell residence time? 42
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General Equation for Mean Cell Residence Time 43
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Secondary Clarifier (Section 11.3.5) 44
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Sludge Volume Index (SVI) 45
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Other Secondary Treatment Options 46
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Sequencing Batch Reactor (SBR) 47
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Aerated Lagoons 48
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Oxidation Ditch 49
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Trickling Filters (Section 11.3.1) 50
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Rotating Biological Contactors (Section 11.3.1) 51
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DISINFECTION Section 11.3.6 UV Generator and Lamps Chlorine Contact Basin 52
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TERTIARY TREATMENT Section 11.4 53
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Wetlands (Section 11.4.3) 54
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EFFLUENT DISCHARGE 55
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Rapid Infiltration 56
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Slow-Rate Land Application 57
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Overland Flow 58
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Discharge to a Stream (Section 8.2.3) Effects: Nitrogen species Biodiversity DO 59
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Discharge to a Stream: DO 60
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Streeter-Phelps Model where D = oxygen deficit = DO sat - DO actual 61
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Critical Point Obtain from dD/dt = 0: 62
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Evaluation of Model Very simple to use But not like nature Assumes steady state Assumes a single discharge Assumes no upstream dispersion Assumes complete mixing Assumes all the BOD is soluble Doesn’t include scouring Doesn’t include DO from algae 63
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Discharge to a Lake (Section 8.2.2) Cougar Lake 64
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Effect on a Lake Cougar Lake 65
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SLUDGE MANAGEMENT Section 11.5 66
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Purpose Reduce/inactivate pathogens Increase solids content Reduce odor & putrescence 67
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Sludge Treatment 68
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Sludge Disposal How can we get rid of the sludge??? And how do we choose which option is best? 69
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OTHER DESIGN ISSUES 70
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ONSITE TREATMENT 71
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Conventional Septic System 72
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Anaerobic Septic Tank 73
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Absorption Fields Shallow Trench Drop Box 74
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Septic Tank with Sand Filter Single Pass (Intermittent) Recirculating 75
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Mound System Plowed Layer (Ground Surface) Topsoil and Vegetation Cover Pipe from Pump (pressure distribution line) Distribution Lateral Marsh Hay Bed of Coarse Aggregate (0.5 - 2”) Sand Fill 76
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Aerobic Treatment Units (ATU) 77
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Lagoon/Waste Stabilization Pond 78
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