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Published byAnastasia Stafford Modified over 9 years ago
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Permanganate and hydrogen peroxide
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Hydrogen peroxide solution is colourless. Permanganate in neutral conditions
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When potassium permanganate solution is added, the purple solution turns brown.
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If you look closely, you can see bubbles of a colourless gas being formed.
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Leave the beaker to settle for 10 minutes and a brown solid is clearly visible.
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Neutral permanganate is reduced to MnO 2 (s): MnO 4 - + 4H + + 3e - → MnO 2 (s) + 2H 2 O purple brown H 2 O 2 → O 2 (g) + 2H + + 2e - 2MnO 4 - + 2H + + 3H 2 O 2 → 2MnO 2 + 4H 2 O + 3O 2
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Fresh hydrogen peroxide solution is acidified with sulfuric acid. We don’t use HCl because the Cl - ion can act as a reducing agent. Permanganate in acid conditions
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Purple permanganate solution turns colourless as it is added to the acidified peroxide.
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Oxygen gas is again produced, but is not visible in this very dilute solution. MnO 4 - + 8H + + 5e - → Mn 2+ + 4H 2 O H 2 O 2 → O 2 + 2H + + 2e - 5H 2 O 2 + 2MnO 4 - + 6H + → 5O 2 + 2Mn 2+ + 8H 2 O
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