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Chapter 12: Solutions.

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1 Chapter 12: Solutions

2 Goals: Read Ch (pg ) Title the notes “Ch 12 Solutions” (in notes section) Copy table 1 pg 402 *summarize/abbreviate as possible Table 2 pg 404 Table 3 pg 404 Read and take notes/ create vocab list Materials, Procedures and Hypothesis for final science fair project: Due Friday Pg 5 and 6 of packet Get PhET activity to start (Friday activity, due next Monday)

3 Section 1- Types of Mixtures
Solutions are homogeneous mixtures of two or more substances in a single phase. Soluble describes a substance as capable of being dissolved. Solvent is the dissolving medium in a solution. Solute is the substance that is dissolved in a solution.

4 Types of Solutions Solutions can be in any of the three common physical states. solid- a mixture of metals called an alloy liquid- salt water, sugar water, Kool-Aid… gas- the atmosphere

5 Suspensions & Colloids
A suspension has large particles that settle out of a solvent. ex. muddy water A colloid has intermediate size particles. Also called an emulsion or a foam.

6 Solutes: electrolytes vs. nonelectrolytes
An electrolyte is a substance that dissolves in water to give a solution that conducts electricity. A nonelectrolyte is a substance that dissolves in water to give a solution that does NOT conduct electricity. Do section review questions #1, #2, & #6 on page 406.

7 Ch 12.2- The Solution Process
Factors that affect the rate of solution (how quickly a substance dissolves): Any process that increases the number of contacts between the solvent and the solute will increase the solution rate. increasing the surface area of the solute agitating (shaking or stirring) the solution heating the solvent

8 Graphs All Graphs Need: Title Labeled axis Units as needed Key:
Dependant variable (units) independent variable (units) All Graphs Need: Title Labeled axis Units as needed Key:

9 Warm up: Compare and contrast molarity and molality.
If given or asked for grams, how do you relate grams to moles?

10 Ex C: Suppose you want to dissolve 205g of Na2CO3 in enough water to make 5.00L of solution. What is the molarity? Molar mass= 106.0g/mol 205/106 =

11 Solubility Vocab Solubility is a measurement of how much solute will dissolve in a specific amount of solvent at a specific temperature to make a saturated solution. “Likes dissolve likes”- polar solvents dissolve polar solutes & nonpolar solvents dissolve nonpolar solutes. Hydration: the solution process with water as the solvent. Hydrates: ionic compounds that have formed crystals that have incorporated water molecules in their structure. Immiscible liquids are not soluble in one another. eg. oil & water Miscible liquids dissolve freely in one another in any proportion. eg. water & alcohol

12 Solutions Solution equilibrium: the physical state in which the opposing processes of dissolution and crystallization occur at equal rates. Dissolution: dissolve Crystallization: form solid

13 Factors that affect the rate of solution: (how quickly a substance dissolves)
Any process that increases the number of contacts between the solvent and the solute will increase the solution rate. Increase solution rate by: increasing the surface area of the solute agitating (shaking or stirring) the solution heating the solvent

14 temp. and pressure affects on solubility:
Increasing the pressure increases the solubility of gases in a liquid. has no effect on the solubility of a solid in a liquid For gas in liquid, increasing temp decreases the solubility. For solid in liquid, increasing temperature often increases the solubility

15 Henry’s Law: the solubility of a gas in a liquid is directly proportional to the partial pressure of the gas on the surface of the liquid. Effervescence is the rapid escape of a gas from a liquid in which the gas is dissolved. A solvated solute particle is surrounded by solvent molecules.

16 saturated solution: contains the maximum amount of dissolved solute.
unsaturated solution: contains less than the maximum amount of dissolved solute. A supersaturated solution: contains more dissolved solute than a saturated solution.

17 Solubility curve Solubility is a measurement of how much solute will dissolve in a specific amount of solvent at a specific temperature to make a saturated solution.

18 Will the solubility increase, decrease, remain the same?
Soda is opened and heated (the gas)? Solid sodium chloride is dissolved is water as it is heated. Carbon dioxide is dissolved in water as it is cooled. Potassium chloride is added to a saturated solution. The surface pressure of salt water is increased. Surface pressure of dissolved oxygen is increased. Decrease Increase Same increase

19 Enthalpy of solution: amount of heat absorbed by a solution when a specific amount of solute dissolves in a solvent.

20 Classwork Solutions Matching
Put in classwork section, number your page and write out the vocab word for answers 2. When done, work on solutions PHeT simulation (see handout section of website) 3. Then work on study guide

21 Classwork Solutions Matching
Put in classwork section, number your page and write out the vocab word for answers Ch 12.3 Practice C and E Answer questions: Pg 421 Practice #1-3 Pg 424 Practice #1-2 Solutions on pg 920

22 Solutions Soluble Solvent Solute Nonelectrolyte miscible Colloid Suspension Supersaturated Saturated unsaturated Electrolyte Solubility immiscible B. Solute Immiscible Colloid Solution, miscible Saturated Electrolyte Solvent suspension

23 12.3 Concentrations of Solutions
The concentration measure of the amount of solute dissolved in a given amount of solvent or solution. Molarity (M) is the number of moles of solute in one liter of solution. M = #mol L Do practice problems #1, #2, & #3 on page 421.

24 Warm up: What is a solution? A solute? A solvent?

25 12.3 Concentrations of Solutions
Molarity (M) is the number of moles of solute in one liter of solution. M = mol L Ex A: pg 420 What is the molarity of a 3.50L solution that contains 90.0g of NaCl Molar mass = 58.44g/mol 90.0g x (1mol/58.44g) = 1.54 mol 1.54 mol = .440 M NaCl 3.50 L Do practice problems #1, #2, & #3 on page 421.

26 How many moles of HCl in 0.8L of a 0.5M solution?
Ex B: How many moles of HCl in 0.8L of a 0.5M solution? M = mol .5M = mol L L .8L(.5mol/L) = .4mol HCl

27 Molality (m) is the concentration of a solution expressed in moles of solute per kilogram of solvent. m = mol kg Ex D: pg 423 A solution dissolved .0500mol C12H22O11 in 125g of water, what is the molal concentration? 125g (1kg/1000g) = .125kg .0500 mol = .400 m C12H22O kg Do practice problems #1 & #2 on page 424.

28 Read Ch12.1-12.2 (pg 400-412.) and take notes in note section of notebook.
Title the notes “Ch 12 Solutions” Copy table 1 pg 401 Table 2 pg 404 Table 3 pg 404 Create a vocab list

29 Graphs All Graphs Need: Title Labeled axis Units as needed Key:
Dependant variable (units) independent variable (units) All Graphs Need: Title Labeled axis Units as needed Key:

30 What are the independent and dependent variables
What are the independent and dependent variables? What is the saturation point of the blue chemical? What unit is used to measure saturation?

31

32 Solubility curve Solubility is a measurement of how much solute will dissolve in a specific amount of solvent at a specific temperature to make a saturated solution.

33

34 Solution Concentrations
Percent composition by mass (%) is a concentration that expresses the percent of solute in a solution. % = #g solute x 100 # g solution Do section review problems #1, #2, & #3 on page 424.

35 matching homogeneous mixtures of two or more substances in a single phase. describes a substance as capable of being dissolved. the dissolving medium in a solution. the substance that is dissolved in a solution. Doe not conduct electricity Liquids that dissolve freely in one another intermediate size particles, also called an emulsion or a foam large particles that settle out of a solvent. Contains more dissolved solute than saturated solution under same conditions Solution containing maximum amount of dissolved solute Contains less solute than possible under the existing conditions Conducts electricity Amount of substance to form a saturated solution under specific conditions Liquids that are not soluble in each other Solutions Soluble Solvent Solute Nonelectrolyte miscible Colloid Suspension Supersaturated Saturated unsaturated Electrolyte Solubility immiscible Soluble Solvent Solute Solutions Solubility Electrolyte Nonelectrolyte Immiscible Miscible Suspention Saturated Unsaturated Supersaturated Colloid

36 Chapter 12 Test Review multiple choice
define & identify suspensions & solutions define an alloy define & identify electrolytes & nonelectrolytes factors that affect the rate of dissolution definitions of unsaturated, saturated & supersaturated solutions general rules for predicting whether a solute is soluble in a solvent definition of solubility effects of temperature & pressure on the solubility of gases and solids in liquids definitions of molarity (M) and molality (m) solving molarity & molality problems FORMULAS: M = #mol/L m = #mol/kg


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