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Lecture 354/26/06
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What does it mean to be radioactive? Radioactivity vs. nuclear power
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Radioactive emissions Alpha particle (α) Helium nucleus
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Radioactive emissions Beta particle (β) electron neutron electron (β) + proton
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Gamma (γ) doesn’t change atomic mass or number Radioactive emissions
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positron (β + ) electron proton positron (β) + neutron
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Radioactive Electron capture Electron + proton neutron
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Rates of radioactive decay Decay is not affected by temperature, pressure, or state of chemical combination
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If you start with 1.5 mg of tritium 3 H, how much is left after 49.2 years? t 1/2 =12.3 years
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Belt of stability (empirically derived) Belt of stability ends at element 83 elements ≥ 84 protons are radioactive Type of decay nuclei above belt of stability (high N/Z) Beta emission 131 I 131 Xe + β decreases N/Z nuclei below the belt of stability (low N/Z) loss of positron of electron capture 11 C 11 B + β + or 81 Rb + e 81 Kr increases N/Z nuclei with atomic # ≥ 84 alpha emission 238 U 234Th + α
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Belt of stability
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Carbon dating in atmosphere t 1/2 =5730 years Ratio of 14 C/ 12 C constant until death, then 14 C/ 12 C decreases At death, 14 C has about 14 disintegrations per minute/gram (dpm/g)
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Carbon-14 limitations 1. assume 14 C in atmosphere is constant 2. can’t date object < 100 years old 3. accuracy only ± 100 years 4. only good back to ~ 40, 000 years
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Stability of Nuclei Out of > 300 stable isotopes: Even Odd Odd Even Z N 15752 505 31 15 P 19 9 F 2 1 H, 6 3 Li, 10 5 B, 14 7 N, 180 73 Ta
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