1. Spin Excitations and Spin Damping in Ultrathin Ferromagnets D. L. Mills Department of Physics and Astronomy University of California Irvine, California Collaborators: R. B.Muniz and A. T. Costa Instituto de Fisica Universidade Federal de Fluminense Niteroi, Brazil

2. Experimental methods for probing spin dynamics In ultrathin magnetic films: 1.Ferromagnetic resonance (FMR): Examines only spin motions. 2. Brillouin light scattering (BLS): (Inelastic scattering of photons): Examines, small on the scale of the Brillouin zone. 3. Inelastic Neutron Scattering : Problems! (i). Not surface sensitive. (ii). Neutrons can’t excite spin excitations in materials of interest; Neutron kinetic energy ~ 30 meV, spin wave energy scale ~ 300 meV. 4. Spin Polarized Electron Energy Loss Spectroscopy: (SPEELS) (i). High surface sensitivity (ii). Lots of beam energy (several eV) (iii). Cross section small.

3. Expectations for Spin Wave Spectrum of an N Layer Ferromagnetic Film: The Heisenberg Model: Spin Wave Excitations: 1. Write down equation of motion for 2. Seek solutions of the form where lies in the 2D Brillouin zone. Conclusion: For each value ofone has N spin wave eigenmodes, each with infinite lifetime.

4. Heisenberg Model Description of the Spin Wave Spectrum of a Five Layer Ferromagnet: For the materials of interest currently, this picture is qualitatively wrong!

5. Our Approach: 1.Place ultrathin, few layer film on a semi infinite substrate. 2. Use empirical tight binding description of electronic structure, with nine bands for each material. Parameters obtained from fits to electronic structure calculations. 3. Ferromagnetism driven by intra atomic Coulomb interactions, with strength taken from photoemission data on exchange splitting (F. Himpsel, J. Magn. & Mag. Mat. 102, 261 (1991)) ) 4. Mean field, self consistent calculation of ground state, with moments allowed to vary on a layer by layer basis. 5. Random Phase Approximation applied to description of spin dynamics.

6. The Fe Monolayer on W(110); Comparison Between Local Density of States in GGA Based Density Functional Calculation (black) and Tight Binding Description. A.T. Costa, R. B. Muniz, J. X. Cao, R. Wu and D.L. Mills (to be published)

7. Spin Excitations In Ultrathin 3d Ferromagnetic Films: The Case of Fe (5 layers) on W(110): A. T. Costa, R. B. Muniz, and D. L. Mills, Phys. Rev. B66, 224435 (2001). Q x =0.05 Q x =0.20

8. Farther out in the Brillouin Zone: Q x =0.4 Q x =0.6

9. Another Example : Eight Layers of Co on Cu(100) A.T.Costa, R. B. Muniz and D. L. Mills, Phys. Rev. B70, 54406 (2004) Q=0.3 Q=0.6

10. An Experiment : Spin Polarized Electron Loss Spectroscopy (SPEELS) Specular Direction Spin Wave Excitation: Angular Momentum Conservation Requires a Spin Flip

11. An Example of Electron Loss Spectroscopy: Surface Phonons on the Ni (100) Surface Experiment: M. L. Xu, B. M. Hall, S. Y. Tong, M. Rocca. H. Ibach and J. E. Black, Phys. Rev. Letters 54, 1171 (1985). Theory: B. M. Hall and D. L. Mills, Phys. Rev. B54, 1171 (1985). What do we expect for spin waves? Theory says  SW /  Ph ~ 10 -3. (M. P. Gokhale, A. Ormeci and D. L. Mills, Phys. Rev. B46, 8978 (1992))

12. SPEELS Studies of Spin Waves in Ultrathin Ferromagnets; Co on Cu(100): R. Vollmer, M. Etzkorn, P. S. Anil Kumar, H. Ibach, and J. Kirschner, Phys. Rev. Letters 91, 147201 (2003) Spin Dependence of the Excitation Process:

13. Comparison Between Theory and Experiment: A. Dispersion Relation of Single Loss Feature: B. Linewidth and Lineshape:

14. The Limit of Zero Wave Vector: It is crucial to understand the spin damping in ultrathin films at long wavelengths; this controls realizable switching speeds in devices. A measure of spin damping: Ferromagnetic resonance linewidths. The Question: Are damping mechanisms the same In ultrathin ferromagnets as in bulk materials? Bulk Ferromagnets: Damping at Q = 0 is a spin orbit based mechanism (Goldstone theorem). Ultrathin Ferromagnets: Two mechanisms not operative in the bulk: 1.“Spin pumping”: Intrinsic. 2.Two magnon scattering: Extrinsic. R. Arias and D. L. Mills, Phys. Rev. B60, 7395 (1999), D. L. Mills and S. M. Rezende, p. 27 of Spin Dynamics in Confined Structures II, (Springer Verlag, Heidelberg, 2002).

15. Calculations of FMR Spectra and Linewidths: A.T. Costa, R. B. Muniz and D. L. Mills (to be Published) 1. Co 2 on Cu(100): 2. Co 2 Cu 2 Co 2 on Cu(100):

16. Comparison Between Theory and Experiment: The Case of Fe on Au(100) Data: R. Urban, G.Woltersdorf and B. Heinrich, Phys. Rev. Letters 87,217204 (2001).

17. Data on Trilayers; Quantum Interference Effects The Data: (K. Lenz, T. Tolinski, J. Lindner, E. Kosubek, and K. Baberschke, Phys. Rev. B69, 14422 (2004). Theory:

18. Concluding Remarks: 1.For large wave vector spin wave excitations in ultrathin ferromagnets, the Heisenberg model description fails qualitatively. The reason is a breakdown of the adiabatic approximation. An effective Heisenberg Hamiltonian can be used to describe static phenomenon (domain walls) but not spin excitations at large wave vectors. 2. Our approach provides a quantitative description of spin excitations and their (intrinsic) damping throughout the two dimensional Brillouin zone, from the FMR regime to the large wave vectors explored in the electron energy loss studies.