1. Christopher J. Kloxin, Research Assistant Professor Materials Science and Engineering Chemical Engineering September 26, 2011 Polymer Networks: The Next Generation (in five minutes…) Research Theme: Creating and developing versatile materials, materials that are synthetically flexible, which enable a large degree of tailoring material properties for specific applications.

2. New Polymerization Chemistries Thiol-yne photopolymerization 1 Iodo-ene photopolymerization 2 1) Fairbanks, Scott, Kloxin, Anseth, and Bowman, Macromolecules 42 (1), 211-217 (2009) 2) Scott and Kloxin, in preparation

3. New Polymer Network Paradigm: Covalent Adaptable Networks 1 Low-Stress Photopolymerization 2 2) Kloxin, Scott, and Bowman, Macromolecules 42 (7) 2551-2556 (2009). 21 43 21 43 1) Kloxin, Scott, Adzima, and Bowman, Macromolecules, 43 (6) 2643-2653 (2010) 3) Adzima, Kloxin, and Bowman, Advanced Materials 22 (25) 2784-2787 (2010) Externally Triggered Material Healing 3

4. Photo-click 1 Mechanophotopatterning 2 Photofixation 3 2) Kloxin, Scott, Park, and Bowman, Adv. Mater. 23 (17) 977 ‐ 1981 (2011) New Methods of Photopatterning 1) Adzima, Tao, Kloxin, DeForest, Anseth, and Bowman, Nature Chem. 3 (3) 258-261 (2011) 3) Adzima, Kloxin, DeForest, Anseth, and Bowman, submitted to Adv. Mater.

5. Future Projects Photorevesible Networks photoreversible adhesives MPP Platform Directed Self-assembly Membranes Data storage and nanoscale electronics Graphene Composites Energy harvesting and storage Funding provided by: Acknowledgements: Prof. Christopher Bowman Prof. Kristi Anseth Prof. Timothy Scott Dr. Brian Adzima Dr. Cole DeForest Dr. Benjamin Fairbanks Dr. Heeyoung Park Contact Information Ph: +1 302 831 8670 E-mail: cjk@udel.educjk@udel.edu Web: www.cjklab.orgwww.cjklab.org

6. Questions? Comments?