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Super-capacitors Vs. Capacitors No conventional dielectric Two layers of the same substrate, result in the effective separation of charge Lack of dielectric results in a packing of layers which result in higher surface area Capacitance can reach Thousands of Farads Two parallel plates with dielectric Limited surface area, limiting capacitance
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Double Layer Capacitor have double layer construction consisting of two carbon electrodes immersed in an organic electrolyte During charging, the electrically charged ions in the electrolyte migrate towards the electrodes of opposite polarity No chemical action equals typical cycle life in hundreds of thousands
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Activated Carbon Vs Carbon Nanotube Carbon NanotubeActivated Carbon(or activated charcoal)
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Activated Carbon: is a form of carbon that has been processed to make it extremely porous and thus to have a very large surface area available for adsorption or chemical reaction. powder made up of extremely small and very "rough" particles, which in bulk form a low-density volume of particles with holes between them that resembles a sponge. The overall surface area allow many more electrons to be stored in any given volume than other conductors such as aluminum. The downside is that the charcoal takes the place of the improved insulators used in conventional devices, so in general electric double-layer capacitors use low potentials on the order of 2 to 3 V.
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Experimental devices developed at MIT replace the charcoal with carbon nanotubes, which have similar charge storage capability as charcoal (which is almost pure carbon) but are mechanically arranged in a much more regular pattern that exposes a much greater suitable surface area. By using vertically aligned, single-wall carbon nanotubes which are only several atomic diameters in width instead of the porous, amorphous carbon normally employed, the effective area of the electrodes (plates) can be dramatically increased. This still won’t achieve the levels of energy of a rechargeable battery, but it will increase the power density
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AdvantagesDisadvantages High power available. High power density. No special charging or voltage detection circuits required. Can be charged and discharged in seconds. Can not be overcharged. Long cycle life of more than 500,000 cycles. No chemical actions. 10 to12 year life Low impedance Linear discharge voltage characteristic prevents use of all the available energy in some applications. Power only available for a very short duration. Low capacity. Low energy density. (6Wh/Kg) High self discharge rate. Much higher than batteries. Upper and lower voltage is limited to main energy source (battery), leading to wasted energy.
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Batteries Vs. Super-Capacitors Super-capacitors can have power densities that are 100 times greater than that of batteries Power density combines the energy density with the speed that the energy can be drawn out of the device Batteries have relatively slow charge and discharge times. Super capacitors offer a more environmentally friendly option than batteries because of their long lifespan. However batteries store more energy than super-capacitors
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Applications Super-capacitors are used to provide fast acting short term power back up for uninterruptable power supply(UPS) applications. Battery life can be extended, with battery super-capacitor combinations. The batteries provide average power and super- capacitors provide short duration peak power boost, reducing the peak loads on the battery and permitting the use of smaller batteries.
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Hybrid Electric Vehicles The CSIRO in australia [national science agency] has developed the UltraBattery, which combines a supercapacitor and a lead acid battery in a single unit 4x longer life cycle, 50% more power, 70% cheaper than batteries used in HEV’s
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