1. Slides 2-4: Agust,www,....rempi/hcl/October08/HClg3S-V9V10-311008ak.ppt & Agust,www,....rempi/hcl/October08/HClg3S-V9V10-031108ak.ppt Agust,heima,..October08/Term values for triplet paper-311008kmak.xls Agust,heima,... kennsla/ArnarH/IGOR/Profun-311008ahak.pxp

2. Spacing between perturbed energy Levels  ) in the 3  - (0 + ), v´=0 state J´(higher)  values for the 3  - (0 + ), v´=0 state   5 0 0 5 5 0

3.  E =2B 0 J – 4D 0 J 3 B 0 = 7.629 cm -1 D 0 = - 5.726 x 10 -3

4.  E =2B 0 J B 0 = 7.629 cm -1

5. Slides 6-7: Agust,www,....rempi/hcl/October08/HClg3S-V9V10-031108ak.ppt Agust,heima,... kennsla/ArnarH/IGOR/Profun-031108ahak.pxp

6. Deperturbed levels according to D. Field et al. Perturbed levels (<= Green et al.) calculated levels: Using W12(v´=9) =266 cm-1 & W12(v´=10) = 589 cm-1 And equation:

7. Least square W12(9) W12(10) 10689.560390 558.11260490 19641.360590 2572.8360515 1144.360500 814.62160495 232.50860473 434.83660464 201.289120490 12.0321255582 8.45215261584 7.10257263586 6.7192264587 6.52643265588 6.52155266589 Tryal and error analysis, assuming homogeneous coupling:

8. => It is worth checking the effect of V, v´=11 (possibly V,v´=8)