Download presentation
Presentation is loading. Please wait.
2
Ar Cl
3
Ar Cl...
4
Ar
5
Cl Ar + -
6
Cl Ar
7
Stilben e(1)
8
Stilbene(2)
9
= HCl Water / H 2 O = i.e.: H 3 O +..... Cl - (aq) HCl + H 2 O(l)
10
H 3 O +..... Cl - (aq) HCl + H 2 O(l) Energy +
11
= HCl(g) = H + Cl - (g) Energy r(HCl) HCl H + Cl H + Cl - H + + Cl -
12
HCl(g) H + Cl - (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl H + Cl - H + + Cl - H 3 O +... Cl - (nxH 2 O) + n x H 2 O
13
HCl(g) H + Cl - (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl H + Cl - H 3 O +... Cl - (nxH 2 O) H + Cl - + H 2 O :::::::::: H + Cl - H + Cl -
14
út HX HX/H 2 O Spíttari Turbo Pumpa TOF rör safnlinsa MCP skynjari sveiflusjá tölva Gas Laser Lit- Laser SHG Pellin Broca prisma Stjórn- eining
15
LASER- tæki jónunarklefar TOF rör
16
Laser excitation: 86616.5 cm -1
17
Mass spectra vs. Laser excitation Laser cm -1 Ion yield
18
Fig. 3 Experimental and calculated REMPI-TOF spectra,
19
E 86616 cm -1 0 (HF)2(HF)2 (HF)2(HF)2 * * 1 2 1 2 * * K = 0K = 1 = 0 * = 0 (n ((n+1) p ( 1, 2 ): (0,0) ( 1, 2 ): (0,0)? ** J J* 36 cm -1 Electronic-, vibrational- and rotational- resonance transitions in the (2+1) REMPI, 86618 cm -1 system.
20
Ab initio/ DFT Orku- lágmörkun H H FF
21
1. Laser ljósefnafræði og litrófsgreining: : Victor Huasheng Wang Gísli Hólmar Jóhannesson, Áshildur Logadóttir Benedikt G. Waage Jón Matthíasson Kristján Matthíasson Ómar Freyr Sigurbjörnsson Oddur Ingólfsson Haraldur Þórðarson Hérlendir samstarfsaðilar * *
22
2. Lögun stilben- og dioxan-afleiða: Jón K.F. Geirsson, Christopher Evans Sigríður Jónsdóttir Ásgeir Konráðsson Benedikt I. Ásgeirsson samstarfsaðilar:
23
3. Lögun Si haldandi efna (NMR o.fl.): Dr. Ingvar Árnason, Dr. Sigríður Jónsdóttir Pálmar I. Guðnason Hérlendir samstarfsaðilar:
Similar presentations
© 2024 SlidePlayer.com. Inc.
All rights reserved.