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Lecture 1410/3/05
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Compare the heights of a Hg barometer and a water barometer if atmospheric pressure is 1 atm. (Density of Hg = 13.53 g/cm 3 )
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A scuba diver taking photos of a coral reef 60 ft below the ocean surface breathes out a stream of bubbles. What is the total gas pressure of the bubbles at the moment they are released? What is the pressure when the bubbles get to the surface?
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Boyle’s Law Pressure vs. Volume As the volume of the air is reduced, its pressure goes up
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Boyle’s Law Assumes constant n and T
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A sample of nitrogen gas has a pressure of 67.5 mm Hg in a 500-mL flask. What is the pressure of this gas sample when it is transferred to a 125-mL flask at the same temperature?
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Charles’ Law Volume vs. Temperature (n and P are constant)
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Charles’s Law As temperature decreases, volume decreases (n and P are constant)
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A balloon is inflated with helium to a volume of 45 L at room temperature (25 o C). If the balloon is cooled to - 10 o C, what is the new volume of the balloon? Assume no change in pressure.
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General Gas Law (Combined Gas Law) Assumes a constant n Boyle’s Law and Charles’ Law are not independent
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You have a 22-L cylinder of helium at a pressure of 150 atm and at 31˚C. How many balloons can you fill, each with a volume of 5.0L on a day when the atmospheric pressure is 755 mm Hg and the temperature is 22˚C.
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Avagadros’s Hypothesis Assumes constant T and P
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Name 3 ways the volume occupied by a sample of gas can be decreased.
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IDEAL GAS LAW Combines: Boyle’s Law Charles’s Law Avagadro’s Law
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Gas Constant (R)
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How much N 2 is required to fill a small room with a volume of 27,000 L to a pressure of 745 mm Hg at 25 o C? R = 0.082057 Latm/Kmol
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A 1.00 g sample of water is allowed to vaporize completely inside a 10.0-L container. What is the pressure of the water vapor at a temperature of 150˚C?
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What is the volume of 1 mole of gas at Standard Temperature (0˚C) and Pressure (1 atm)?
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Gas Density How do you introduce density into the ideal gas law?
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Calculate the density of dry air at 25˚C and 1.00 atm if its molar mass (average) is 28.96 g/mol.
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Prove that putting Helium in a balloon will make it rise.
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In August 1986, 1700 people died from asphyxiation in the Lake Nyos valley, Camaroon, as a result of the lake’s massive release of carbon dioxide that blanketed the valley. Calculate the density of CO 2 at 1 atm and 298 K.
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