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Lecture 5 Vibrational Spectra of Simple Molecules
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Diatomic Molecules Rotations Reduced mass Moment of inertia Convenient units: cm -1 To convert, we divide energy in joules by 100hc 1.989 ×10 -23 For I =1 (a.e.×Å 2 ) B=16.9 cm -1
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Related thermal population of rotational levels in CO molecule at room temperature
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Vibrations of Diatomic Molecules
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Temperature dependence of spectra Lactose IR Raman CCl 4 @460 cm -1 Freeze it!
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http://webbook.nist.gov/chemistry/name-ser.html
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http://www.chemtube3d.com/vibrationsHCN.htm CO 2
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