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Pnt I rel AK: 200307; agust,heima/rannsóknir/REMPI/HF/fra Wang/HF test skimmer-200307.pxp & HF t skimmer-200307.ppt Fig. 1.

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Presentation on theme: "Pnt I rel AK: 200307; agust,heima/rannsóknir/REMPI/HF/fra Wang/HF test skimmer-200307.pxp & HF t skimmer-200307.ppt Fig. 1."— Presentation transcript:

1 pnt I rel AK: 200307; agust,heima/rannsóknir/REMPI/HF/fra Wang/HF test skimmer-200307.pxp & HF t skimmer-200307.ppt Fig. 1

2 LASER wavenumbers AK: 200307, REMPI spectra recorded for max intensities of all ion Species; Hence signal near 21654.5 (86618 cm-1 = 2 x hv excitation) Drops out in lower spectrum since resonance signal is lower than “background” signal (which most probably is due to C+). Width of spectrum is about 4 cm -1 on 2 x hv excitation scale Fig. 2

3 21655.9 cm-1 86618 cm-1 (2hv) pnt Irel 21656.0 cm-1 21656.1 cm-1 21655.8 cm-1 21655.7 cm-1 Fig. 3

4 pnt Sqrt(Mw) Pnt = 57.197 (Mw) 1/2 + 23.819 Mw for peak at pnt = 363 is Mw = ((363-23.819)/57.197) 2 = 35.1 Fig. 4

5 200307, HF:Ar=20:80 www,agust/../ HF t-skimmer-200307.ppt & Agust,heima/../ HF test with skimmer-20307a-ak pnt Irel Fig. 5

6 200307, HF:Ar=20:80 www,agust/../ HF t-skimmer-200307.ppt & Agust,heima/../ HF test with skimmer-20307a-ak pnt Irel Fig. 6

7 200307, HF:Ar=20:80 www,agust/../ HF t-skimmer-200307.ppt & Agust,heima/../ HF test with skimmer-20307a-ak “difference spectrum” 21655.7-21654.8(bgr.) pnt Irel Fig. 7

8 200307, HF:Ar=20:80 www,agust/../ HF t-skimmer-200307.ppt & Agust,heima/../ HF test with skimmer-20307a-ak pnt Irel Fig. 8

9 200307, HF:Ar=20:80 www,agust/../ HF t-skimmer-200307.ppt & Agust,heima/../ HF test with skimmer-20307a-ak “difference spectrum” 21654.3-21654.8(bgr.) pnt Irel Fig. 9

10 Fig. 10

11 pnt Irel 200307, HF:Ar=20:80 www,agust/../ HF t-skimmer-200307.ppt & Agust,heima/../ HF test with skimmer-20307a-ak 21654.3 & 21655.7 mass spectra => HCl: 35 Cl H 35 Cl 37 Cl H 37 Cl Fig. 11 See http://www.raunvis.hi.is/~agust/rempisvaedidir/rempitof/retohcl.htm for comparisonhttp://www.raunvis.hi.is/~agust/rempisvaedidir/rempitof/retohcl.htm


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