Presentation is loading. Please wait.

Presentation is loading. Please wait.

ADSORPTION ISOTHERMS discontinuous jumps: layering transitions some layering transitions coexistence pressure monolayer condensation bilayer condensation.

Similar presentations


Presentation on theme: "ADSORPTION ISOTHERMS discontinuous jumps: layering transitions some layering transitions coexistence pressure monolayer condensation bilayer condensation."— Presentation transcript:

1

2

3

4

5 ADSORPTION ISOTHERMS discontinuous jumps: layering transitions some layering transitions coexistence pressure monolayer condensation bilayer condensation

6  = 0.45 0.60

7 two-phase region liquid-vapour transition of monolayer two-phase region

8 at two-phase coexistence

9

10

11  

12

13

14 Y(s)Y(s) Y (  s ) = Q (  s )

15 if there exists  such that there is a wetting transition, this is of 2 nd order Y(s)Y(s)

16 COMPLETE WETTING T=T W COMPLETE WETTING T>T W PARTIAL WETTING T<T W PARTIAL WETTING T<T W

17 area under curve

18

19

20

21 contribution from hard interaction contribution from attractive interaction (with correlations = step function)

22

23

24

25

26

27 a  b  a  < s a(T W )  a  b  s <


Download ppt "ADSORPTION ISOTHERMS discontinuous jumps: layering transitions some layering transitions coexistence pressure monolayer condensation bilayer condensation."

Similar presentations


Ads by Google