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ADSORPTION ISOTHERMS discontinuous jumps: layering transitions some layering transitions coexistence pressure monolayer condensation bilayer condensation
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= 0.45 0.60
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two-phase region liquid-vapour transition of monolayer two-phase region
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at two-phase coexistence
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Y(s)Y(s) Y ( s ) = Q ( s )
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if there exists such that there is a wetting transition, this is of 2 nd order Y(s)Y(s)
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COMPLETE WETTING T=T W COMPLETE WETTING T>T W PARTIAL WETTING T<T W PARTIAL WETTING T<T W
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area under curve
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contribution from hard interaction contribution from attractive interaction (with correlations = step function)
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a b a < s a(T W ) a b s <
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