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Noble Gases Groundwater recharge temperatures He Ne Ar Kr Xe.

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Presentation on theme: "Noble Gases Groundwater recharge temperatures He Ne Ar Kr Xe."— Presentation transcript:

1 Noble Gases Groundwater recharge temperatures He Ne Ar Kr Xe

2 Gaz nobles Groupe 18

3 Noble gas solubilities and temperature

4

5 Solubility in Brines

6 PINCH IT!

7 Diffusion Sampler Diffusion Sampler Design

8 Ne Diffusion Sampler

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10 Case study – Bunter Sandstone, UK

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12 Down-gradient evolution of a 14 C and  13 C in groundwaters from the Bunter sandstone. The inverse correlation of a14C with d13C demonstrates the effect of non-decay reaction in attenuating 14C. Fig. 8-9 Down-gradient evolution of a  C and  13 C in groundwaters from the Bunter sandstone. The inverse correlation of a  C with  13 C demonstrates the effect of non-decay reaction in attenuating  C.

13 Noble gas isolation and measurement by quadrupole mass spectrometry Ian, I don’t think it’ll work on Mars.

14 Isotope dilution method AtmosphereSpike Vol - unknown Vol - known 4 He 3 He 20 Ne 22 Ne 40 Ar 36 Ar 84 Kr 78 Kr 132 Xe 136 Xe Andrews, J.N., N. Hussain, and M.J. Youngman, 1989. Atmospheric and radiogenic gases in groundwaters from the Stripa granite. Geochimica et Cosmochimica Acta 53, 1831-1841. Poole, Jason C., Gavin McNeill, Stephen R. Langman, and Frank Dennis (1997). Analysis of noble gas in water using a quadrupole mass spectrometer in static mode. Applied Geochemistry 12: 707-714. Pinti, Daniele L., and Eddy Van Drom (1998). PALEOTEMP: A Mathematica® program for evaluating paleotemperatures from the concentration of atmosphere-derived noble gases in ground water. Computers and Geosciences 24: 33-41.

15 Isotope Dilution AtmosphereSpike Vol - unknown Vol - known 4 He 3 He 20 Ne 22 Ne 40 Ar 36 Ar 84 Kr 78 Kr 132 Xe 136 Xe R 84/78 = —–––– V Kr(atm) V Kr(spike)

16 3 He 4 He geothermal studies groundwater age ( 4 He from  decay) tritium/He dynamics

17 Clark, I.D. and Phillips, R.J., 2000. Geochemical and 3 He/ 4 He evidence for mantle and crustal contributions to geothermal fluids in the western Canadian continental margin. Journal of Volcanology and Geothermal Research, 104: 261-276


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