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Second Quantization -- Fermions Do essentially the same steps as with bosons. Order all states and put in ones and zeros for filled and unfilled states respectively. Example: three particle system
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Slater Determinant Slater determinate Makes wave function antisymmetric Keeps track of signs for f ’s. E’ i ’s are ordered. Only the N occupied states go into determinant. Occupation number space
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Fermion Anticommutators 1. Two particles cannot be in the same state. 2. 0,1 are eigenvalues of number operator. 3. Going to creation and annihilation operators
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Phases for Occupation States Again define occupation state as: where n i =0,1 Need to be careful of phases for raising and lowering operators: Phases become 1 for number operator!
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Phase Factor in Hamiltonian Reorder both sides to normal order. (First move the W to where E k should be; then move it to its proper position. Phase factor depends on whether W>E k or <E k Define:
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Continued First term always there. Second and third term may be present iff: Remembering: Coupled Equations
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Going to Second Quantization
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Green Term Continued Likewise for two other kinetic energy terms (see problem sets). Put delta functions in explicitly Go to “after” n’s
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Potential Energy Term k level is now occupied. Must include in sum as we move to the l level. This is the term i<j<k<l.
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Green Term Likewise for other terms (see problem sets). Sign from extra -1 in phase Reorder to restore + in front
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Both Kinetic and Potential Terms Second Quantization Result Note order to preserve sign.
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