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Chapter 3 Chemical Compounds
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Compounds combination of two or more elements molecular formulas for molecular compounds empirical formulas for ionic compounds K 2 Cr 2 O 7
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Naming Binary Molecular Compounds Usually more metallic nonmetal first then change ending of second to –ide Use Greek prefixes for number, omit mono- for first nonmetal 1.Mono- 2.Di- 3.Tri- 4.Tetra- 5.Penta- 6.Hexa- 7.Hepta-
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Binary Molecular Compounds H 2 Owater NH 3 ammonia H 2 Shydrogen sulfide COcarbon monoxide CS 2 carbon disulfide N 2 O 4 dinitrogen tetroxide CCl 4 carbon tetrachloride
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Which of the following compounds is NOT named correctly? 1.NO 2 nitrogen dioxide 2.S 2 Cl 2 disulfur dichloride 3.OF 2 oxygen difluoride 4.ClFchlorine fluoride 5.SiCl 4 silicon tetrachloride
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Organic Compounds - Ethanol Condensed formulaMolecular formula CH 3 CH 2 OH C 2 H 6 O
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Hydrocarbons alkanes – C n H 2n+2 –octane alkenes – C n H 2n –Ethylene alkynes – C n H 2n-2 –acetylene C=C H HH H H―C≡C―H
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Alkanes – C n H 2n+2 methane – CH 4 ethane – C 2 H 6 propane – C 3 H 8 butanes – C 4 H 10 pentanes – C 5 H 12 hexanes – C 6 H 14 heptanes – C 7 H 16 octanes – C 8 H 18 nonanes – C 9 H 20 decanes – C 10 H 22
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Butane Butane molecules are present in the liquid and gaseous states in the lighter
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Alcohols Replace ―H with ―OH
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Alkanes and their Alcohols
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Straight & Branch-Chain Alkanes
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Some Common Alkyl Groups
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Alkane Isomers
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Naming Branch-Chain Alkanes select the longest chain alkane as the base name determine the side chains and give them a number corresponding to the carbon number on the base chain use Greek prefixes of mono-(1), bi-(2), tri(3), etc. for multiplicity of same side chain
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Naming Branch-Chain Alkanes 2,2,4-trimethylpentane or iso-octane
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The correct name for this compound is? CH 3 ―CH 2 ―CH―CH 2 ―CH 3 C2H5C2H5 1.3-ethylpropane 2.3-methylpentane 3.3-ethylpentane 4.heptane 5.2-ethylpentane
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Cyclic hydrocarbons
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IonicCompounds Characteristics of compounds with ionic bonding: non-volatile, thus high melting points solids do not conduct electricity, but melts (liquid state) do many, but not all, are water soluble
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Formation of Ionic Compound, NaCl
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Valance, Charge on Ions compounds have electrical neutrality metals form positive monatomic ions non-metals form negative monatomic ions balance charges Al 3+ O 2- Al 2 O 3
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Valence of Metal Ions Monatomic Ions Group IA +1 Group IIA +2 Maximum positive valence equals Group A #
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Valence of Non-Metal Ions Monatomic Ions Group VIA -2 Group VIIA -1 Maximum negative valence equals (8 – Group A #)
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Charges on Some Common Monatomic Cations and Anions
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Common metals with only one ion Al 3+ Zn 2+ Ag +
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Polyatomic Ions
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-ate and -ite NO 3 - nitrate NO 2 - nitrite -ate is great, -ite is slight -ate has one more oxygen than –ite hypo-underone less per-completelyone more
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Name other ions by analogy with element above SeO 4 2- selenate BrO 3 - bromate HSe - hydrogen selenide H 2 AsO 4 - dihydrogen arsenate
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Permanganate is? 1.MnO 2 - 2.MgO 4 - 3.MnO 4 2- 4.MnO 4- 5.MnO 4 -
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IO - is? 1.hypoiodite 2.iodite 3.iodide 4.iodate 5.iodine monoxide
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