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Update 2 April 2, 2010 JESUS GUARDADO, LEAH NATION, HUY NGUYEN, TINA RO
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Agenda Project Background Fabrication Testing Project Changes Schedule Flexible Cell http://www.worldofrenewables.com
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Project Background Polymeric Photovoltaic Cells o Low fabrication costs o Fast processing speed o Light weight o Flexible Carbon Nanotubes o Aid transfer of electrons o Prevents charge recombination o Improves Voc, Jsc o $8 per m2 SWeNT SG 65, from CoMoCAT
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Fabrication & Testing Update Assembled 10 samples: Prepared solutions Spin-coated onto substrates Deposited electrode Testing Efficiency calculation via I-V curve Optical absorption range via UV-vis spectroscopy
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Testing UV-Vis o verified CNT presence o gauged absolute effect of CNTs in CNT/P3HT mix I-V Curve o resistors, not diodes Uv-vis w/ NIR in ISN lab
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Results: UV-Vis
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Results: I-V Curves Sample Result Desired Diode Curve
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Analysis Samples weren't diodes P3HT:CNT layer too thin TiO2 too conductive pattern transparent scotch tape Chloroform evaporates too quickly nonuniform coats Cell Pattern ONE Lab
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Modifications FTO instead of ITO substrate availability 4 devices per glass slide more devices to test precise tape placement separate CNT from P3HT spin coat separately P3HT solvent -> dichlorobenzene: Higher boiling point 40mg/mL, before 10mg/mL www.mse.edu
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Layer Separation
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New Cell Design Original CellNew Cell FTO - Fluoride Tin Oxide PEDOT - Poly(3,4-ethylenedioxythiophene) P3HT - poly(3-hexylthiophene)
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Current Progress & Future Schedule
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Thank you. Questions? You may reach us at nanosol@mit.edu http://web.mit.edu/course/3/3.042/team1_10
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