1. CF3Br agust,heima,....Mars11/XLS-310311ak.xls agust,www,......April11/PPT-010411ak.xls agust,heima,....Mars11/PXP-310311ak.pxp agust,heima,....Mars11/CF3HBr REMPI Spectra-290311vhw.pxp agust,heima,....Mars11/CF3HBr REMPI Spectra-290311vhw-110411ak.pxp

2. Quantum defects (  ), summary: spdf 321232123212 CH3Br2.552.580.97 CF3Br2.973.12.71 Br22.942.971.31.28 Br3.142.691.3 ath CH3Br agust,heima,...Mars11/XLS-310311ak.xls 1) Derived by fit in agust,heima,....Mars11/PXP-310311ak.pxp 1)

3. 3/2;5p;d=2.40 75803 X(3/2) 91979.4 X(1/2) 94366.8 ½; 5p;d=2.36 75803 X(3/2) 91979.4 3/2;6p;d=2.38 83455 Possible np (->X) Rydberg states(?): agust,heima,....Mars11/CF3HBr REMPI Spectra-290311vhw.pxp; Lay:3; Gr:0 CF 3 + 1D-REMPI and abs. spectrum CF 3 + 1D-REMPI abs. spectrum

4. X(3/2);5p;  =2.40 75803 X(3/2) 91979.4 X(1/2) 94366.8 X(½); 5p;  =2.36 75803 X(1/2) 94366.8 X(3/2);4d;  =0.83 83455 X(3/2) 91979.4 X(3/2);4d;  =0.91 80515 A(½) 98077.0 A(1/2);5p;  =2.39 81967 Possible 5p (->X(3/2&1/2) and A(1/2)) and 4d (->X(3/2&1/2) Rydberg states(?): 560 540  =2  =0  =2 Vibrational bands agust,heima,....Mars11/CF3HBr REMPI Spectra-290311vhw.pxp; Lay:3; Gr:0

5. Rel. CF 3 * Fluorescene ref: Suto & Lee (´83) Rel. Abs. agust,heima,....Mars11/CF3HBr REMPI Spectra-290311vhw-110411ak.pxp; Lay:3; Gr:0

6. There is no clear correlation between the CF3* fluorescenec and the CF3* 1D REMPI spectrum whereas there is a correlation between the CF3* 1D REMPI spectrum and the absorption spectrum in the sence that the major REMPI spectrum fits the absorption due to transition to the 5p Rydberg state

7. Br atom 1D-REMPI and abs. spectrum agust,heima,....Mars11/CF3HBr REMPI Spectra-290311vhw.pxp; Lay:4; Gr:1