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Agust,heima,....january09/Energy spacings-260209ak.ppt.

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Presentation on theme: "Agust,heima,....january09/Energy spacings-260209ak.ppt."— Presentation transcript:

1 agust,heima,....january09/Energy spacings-260209ak.ppt

2 Term g3Sp1(v= 0) New State Q 82541,7 82582,3 82643,7 82725,7 82827,9 82950,2 83092,2 83253,1 DEDE(DE) (New state) 40,6 61,420,8 8220,6 102,220,2 122,320,1 14219,7 160,918,9 J' 0 1 2 3 4 5 6 7 8 J´(higher) agust, heima,...january09/Term values for triplet paper-260209kmak.xls

3 f3D1,v´=1DE(f3D1) av. Terms: 82544,04 82585,4841,44267 82647,2961,80733 82729,8482,54981 82832,47102,6335 82957,29124,8172 83100,74143,4541 J´ 1 2 3 4 5 6 7 agust, heima,...january09/Term values for triplet paper-190209kmak.xls  E J´,J´-1 J´(higher) DE(DE) 20,36466 20,74248 20,08369 22,18366 18,6369

4 f3D2,v´=0DE(f3D2) av. terms 82079,9 82145,1565,24929 82231,2686,11146 82338,08106,8243 82465,63127,5489 82613,74148,1048 J´ 2 3 4 5 6 7 agust, heima,...january09/Term values for triplet paper-190209kmak.xls  E J´,J´-1 J´(higher) DE(DE) 20,86217 20,71284 20,72462 20,55592

5 f3D3 av.terms 81939,77 82014,84 82109,55 82222,79 82351,29 82491,42 J´ 3 4 5 6 7 8 DE(f3D3) 75,06772 94,71128 113,2378 128,4986 140,1291 From Green From VHW agust, heima,...january09/Term values for triplet paper-190209kmak.xls

6 Coefficient values ± one standard deviation a = -1.0863 ± 1.63 b = 19.085 ± 0.322 f3D3(v´=0)  E J´,J´-1 J´(higher) D=4.0101 D=11.4646 agust,heima,...january09/Profun-19209ak.pxp

7 EstimatedEstimatde f3D3 termsQ lines 81939,7781814,5 82014,8481806,4 82109,5581796,7 82222,7981784,9 82355,381772,47 82502,8881754,14 f3D3 av.terms 81939,77 82014,84 82109,55 82222,79 82351,29 82491,42 Q Green 81814,5 81806,4 81796,7 81784,9 81768,46 81742,68 VHW J´ 3 4 5 6 7 8 agust, heima,...january09/Term values for triplet paper-190209kmak.xls

8 Predicted positions for J´=7 & 8 lines Agust,heima,...f3Delta3/HCl f3d3alignment-190209vhwak.pxp

9 agust,heima,...january09/Profun-100209ak.pxp <= agust, heima,...january09Term values for triplet paper-100209kmak.xls 6 6

10 DE(d3Pi1)J´ 1 39,256292 58,543893 77,949814 97,265065 112,23166 137,20817 d3Pi1 av. Terms 81792,49 81831,75 81890,29 81968,24 82065,5 82177,74 82314,94 All values from Green  E J´,J´-1 J´(higher) agust, heima,...january09/Term values for triplet paper-190209kmak.xls

11 DE(f3D3- d3Pi1) 49,48244 46,60034 44,04656 45,05279 36,34324 J´ 1 2 3 4 5 6 7 agust, heima,...january09/Term values for triplet paper-190209kmak.xls J´  E J´


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